Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/95422
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | en_US |
dc.contributor | Mainland Development Office | en_US |
dc.contributor | Department of Applied Physics | en_US |
dc.creator | Xue, Q | en_US |
dc.creator | Ng, BKY | en_US |
dc.creator | Man, HW | en_US |
dc.creator | Wu, TS | en_US |
dc.creator | Soo, YL | en_US |
dc.creator | Li, MM | en_US |
dc.creator | Kawaguchi, S | en_US |
dc.creator | Wong, KY | en_US |
dc.creator | Tsang, SCE | en_US |
dc.creator | Huang, B | en_US |
dc.creator | Lo, TWB | en_US |
dc.date.accessioned | 2022-09-19T02:00:48Z | - |
dc.date.available | 2022-09-19T02:00:48Z | - |
dc.identifier.issn | 2041-6520 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/95422 | - |
dc.language.iso | en | en_US |
dc.publisher | Royal Society of Chemistry | en_US |
dc.rights | © 2022 The Author(s). Published by the Royal Society of Chemistry | en_US |
dc.rights | This article is licensed under a Creative Commons Attribution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/). | en_US |
dc.rights | The following publication Xue, Q., Ng, B. K. Y., Man, H. W., Wu, T. S., Soo, Y. L., Li, M. M., ... & Lo, T. W. B. (2022). Controlled synthesis of Bi-and tri-nuclear Cu-oxo nanoclusters on metal–organic frameworks and the structure–reactivity correlations. Chemical science, 13(1), 50-58 is available at https://doi.org/10.1039/D1SC05495C. | en_US |
dc.title | Controlled synthesis of Bi- And tri-nuclear Cu-oxo nanoclusters on metal-organic frameworks and the structure-reactivity correlations | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 50 | en_US |
dc.identifier.epage | 58 | en_US |
dc.identifier.volume | 13 | en_US |
dc.identifier.issue | 1 | en_US |
dc.identifier.doi | 10.1039/d1sc05495c | en_US |
dcterms.abstract | Precisely tuning the nuclearity of supported metal nanoclusters is pivotal for designing more superior catalytic systems, but it remains practically challenging. By utilising the chemical and molecular specificity of UiO-66-NH2(a Zr-based metal-organic framework), we report the controlled synthesis of supported bi- and trinuclear Cu-oxo nanoclusters on the Zr6O4nodal centres of UiO-66-NH2. We revealed the interplay between the surface structures of the active sites, adsorption configurations, catalytic reactivities and associated reaction energetics of structurally related Cu-based ‘single atoms’ and bi- and trinuclear species over our model photocatalytic formic acid reforming reaction. This work will offer practical insight that fills the critical knowledge gap in the design and engineering of new-generation atomic and nanocluster catalysts. The precise control of the structure and surface sensitivities is important as it can effectively lead to more reactive and selective catalytic systems. The supported bi- and trinuclear Cu-oxo nanoclusters exhibit notably different catalytic properties compared with the mononuclear ‘Cu1’ analogue, which provides critical insight for the engineering of more superior catalytic systems. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Chemical science, 7 Jan. 2022, v. 13, no. 1, p. 50-58 | en_US |
dcterms.isPartOf | Chemical science | en_US |
dcterms.issued | 2022-01-07 | - |
dc.identifier.scopus | 2-s2.0-85121868762 | - |
dc.identifier.ros | 2021003727 | - |
dc.identifier.eissn | 2041-6539 | en_US |
dc.description.validate | 202209 bchy | en_US |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | CDCF_2021-2022 | - |
dc.description.fundingSource | RGC | en_US |
dc.description.fundingSource | Others | en_US |
dc.description.fundingText | National Natural Science Foundation of China | en_US |
dc.description.pubStatus | Published | en_US |
dc.identifier.OPUS | 70676495 | - |
dc.description.oaCategory | CC | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Xue_Controlled_synthesis_Bi-.pdf | 2.06 MB | Adobe PDF | View/Open |
Page views
88
Last Week
0
0
Last month
Citations as of Oct 13, 2024
Downloads
34
Citations as of Oct 13, 2024
SCOPUSTM
Citations
5
Citations as of Oct 17, 2024
WEB OF SCIENCETM
Citations
4
Citations as of Oct 17, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.