Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/90890
Title: | C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines | Authors: | Habib, A Riaz, S Ahmad, I Najaf Iqbal, D Kamal, S |
Issue Date: | Feb-2021 | Source: | Saudi chemical society. Journal , Feb. 2021, v. 25, no. 2, 101178 | Abstract: | This manuscript reports successful C-H nickellation of the aryl phosphinites (i-Pr2P(O-aryl) derived from un-substituted/substituted phenols: C6H5OH, 4-R-C6H4OH (R = F, MeO). Nickellation was observed with the phosphinites at an ortho-C-H position to generate Br-bridged dimers [{κP,κC-(i-Pr)2PO-aryl}cNi(μ-Br)]2 (C1-C3). While conversion of monomeric complexes from dimeric cyclonickellated complexes, functionalization behaviour was studied under inert atmosphere by reacting synthesized complexes with R2PX in various solvents. In order to understand the feasibility of the reaction and to evaluate the properties of product of insertion, phosphinite-phosphine nickel complexes were also approached from a second side. Appearance of specific signals in NMR spectra of products, provided strong evidences of formation of the target products exhibiting fluxional behaviour. | Keywords: | Cyclonickellation Functionalization Insertion Phosphinites |
Publisher: | Elsevier BV | Journal: | Saudi chemical society. Journal | ISSN: | 1319-6103 | EISSN: | 2212-4640 | DOI: | 10.1016/j.jscs.2020.101178 | Rights: | © 2020 The Authors. Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). The following publication Habib, A., Riaz, S., Ahmad, I., Iqbal, D. N., & Kamal, S. (2021). C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni (II) complexes with chlorophosphines. Journal of Saudi Chemical Society, 25(2), 101178 is available at https://doi.org/10.1016/j.jscs.2020.101178 |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
1-s2.0-S1319610320301678-main.pdf | 2.89 MB | Adobe PDF | View/Open |
Page views
40
Last Week
0
0
Last month
Citations as of May 5, 2024
Downloads
20
Citations as of May 5, 2024
SCOPUSTM
Citations
1
Citations as of May 3, 2024
WEB OF SCIENCETM
Citations
1
Citations as of May 2, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.