Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/90890
DC Field | Value | Language |
---|---|---|
dc.contributor | Institute of Textiles and Clothing | - |
dc.creator | Habib, A | - |
dc.creator | Riaz, S | - |
dc.creator | Ahmad, I | - |
dc.creator | Najaf Iqbal, D | - |
dc.creator | Kamal, S | - |
dc.date.accessioned | 2021-09-03T02:34:55Z | - |
dc.date.available | 2021-09-03T02:34:55Z | - |
dc.identifier.issn | 1319-6103 | - |
dc.identifier.uri | http://hdl.handle.net/10397/90890 | - |
dc.language.iso | en | en_US |
dc.publisher | Elsevier BV | en_US |
dc.rights | © 2020 The Authors. Published by Elsevier B.V. on behalf of King Saud University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). | en_US |
dc.rights | The following publication Habib, A., Riaz, S., Ahmad, I., Iqbal, D. N., & Kamal, S. (2021). C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni (II) complexes with chlorophosphines. Journal of Saudi Chemical Society, 25(2), 101178 is available at https://doi.org/10.1016/j.jscs.2020.101178 | en_US |
dc.subject | Cyclonickellation | en_US |
dc.subject | Functionalization | en_US |
dc.subject | Insertion | en_US |
dc.subject | Phosphinites | en_US |
dc.title | C-Ni bond functionalization in the reaction of binuclear cyclometallated Ni(II) complexes with chlorophosphines | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.volume | 25 | - |
dc.identifier.issue | 2 | - |
dc.identifier.doi | 10.1016/j.jscs.2020.101178 | - |
dcterms.abstract | This manuscript reports successful C-H nickellation of the aryl phosphinites (i-Pr2P(O-aryl) derived from un-substituted/substituted phenols: C6H5OH, 4-R-C6H4OH (R = F, MeO). Nickellation was observed with the phosphinites at an ortho-C-H position to generate Br-bridged dimers [{κP,κC-(i-Pr)2PO-aryl}cNi(μ-Br)]2 (C1-C3). While conversion of monomeric complexes from dimeric cyclonickellated complexes, functionalization behaviour was studied under inert atmosphere by reacting synthesized complexes with R2PX in various solvents. In order to understand the feasibility of the reaction and to evaluate the properties of product of insertion, phosphinite-phosphine nickel complexes were also approached from a second side. Appearance of specific signals in NMR spectra of products, provided strong evidences of formation of the target products exhibiting fluxional behaviour. | - |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Saudi chemical society. Journal , Feb. 2021, v. 25, no. 2, 101178 | - |
dcterms.isPartOf | Saudi chemical society. Journal | - |
dcterms.issued | 2021-02 | - |
dc.identifier.scopus | 2-s2.0-85099197584 | - |
dc.identifier.eissn | 2212-4640 | - |
dc.identifier.artn | 101178 | - |
dc.description.validate | 202109 bcvc | - |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_Scopus/WOS | en_US |
dc.description.pubStatus | Published | en_US |
Appears in Collections: | Journal/Magazine Article |
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File | Description | Size | Format | |
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1-s2.0-S1319610320301678-main.pdf | 2.89 MB | Adobe PDF | View/Open |
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