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http://hdl.handle.net/10397/88830
Title: | Unusual magnetic field responsive circularly polarized luminescence probes with highly emissive chiral europium(III) complexes | Authors: | Zhang, JH Dai, LX Webster, AM Chan, WTK Mackenzie, LE Pal, R Cobb, SL Law, GL |
Issue Date: | Jan-2021 | Source: | Angewandte chemie international edition, Jan. 2021, v. 60, no. 2, p. 1004-1010 | Abstract: | Chirality is ubiquitous within biological systems where many of the roles and functions are still undetermined. Given this, there is a clear need to design and develop sensitive chiral optical probes that can function within a biological setting. Here we report the design and synthesis of magnetically responsive Circularly Polarized Luminescence (CPL) complexes displaying exceptional photophysical properties (quantum yield up to 31 % and |g(lum)| up to 0.240) by introducing chiral substituents onto the macrocyclic scaffolds. Magnetic CPL responses are observed in these chiral Eu-III complexes, promoting an exciting development to the field of magneto-optics. The |g(lum)| of the D-5(0) -> F-7(1) transition increases by 20 % from 0.222 (0 T) to 0.266 (1.4 T) displaying a linear relationship between the Delta g(lum) and the magnetic field strength. These Eu-III complexes with magnetic CPL responses, provides potential development to be used in CPL imaging applications due to improved sensitivity and resolution. | Keywords: | Chirality Circularly polarized luminescence Lanthanide Magnetic properties |
Publisher: | Wiley-VCH | Journal: | Angewandte chemie international edition | ISSN: | 1433-7851 | EISSN: | 1521-3773 | DOI: | 10.1002/anie.202012133 | Rights: | © 2021 THE AUTHORS. Published by Elsevier BV on behalf of Faculty of Engineering, Ain Shams University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). The following publication J. Zhang, L. Dai, A. M. Webster, W. T. K. Chan, L. E. Mackenzie, R. Pal, S. L. Cobb, G.-L. Law, Angew. Chem. Int. Ed. 2021, 60 (2), 1004-1010 is available at https://dx.doi.org/10.1002/anie.202012133 |
Appears in Collections: | Journal/Magazine Article |
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