Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/88830
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | - |
dc.contributor | Chinese Mainland Affairs Office | - |
dc.creator | Zhang, JH | en_US |
dc.creator | Dai, LX | en_US |
dc.creator | Webster, AM | en_US |
dc.creator | Chan, WTK | en_US |
dc.creator | Mackenzie, LE | en_US |
dc.creator | Pal, R | en_US |
dc.creator | Cobb, SL | en_US |
dc.creator | Law, GL | en_US |
dc.date.accessioned | 2020-12-22T01:08:16Z | - |
dc.date.available | 2020-12-22T01:08:16Z | - |
dc.identifier.issn | 1433-7851 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/88830 | - |
dc.language.iso | en | en_US |
dc.publisher | Wiley-VCH | en_US |
dc.rights | © 2021 THE AUTHORS. Published by Elsevier BV on behalf of Faculty of Engineering, Ain Shams University. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). | en_US |
dc.rights | The following publication J. Zhang, L. Dai, A. M. Webster, W. T. K. Chan, L. E. Mackenzie, R. Pal, S. L. Cobb, G.-L. Law, Angew. Chem. Int. Ed. 2021, 60 (2), 1004-1010 is available at https://dx.doi.org/10.1002/anie.202012133 | en_US |
dc.subject | Chirality | en_US |
dc.subject | Circularly polarized luminescence | en_US |
dc.subject | Lanthanide | en_US |
dc.subject | Magnetic properties | en_US |
dc.title | Unusual magnetic field responsive circularly polarized luminescence probes with highly emissive chiral europium(III) complexes | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 1 | en_US |
dc.identifier.spage | 1004 | - |
dc.identifier.epage | 8 | en_US |
dc.identifier.epage | 1010 | - |
dc.identifier.volume | 60 | - |
dc.identifier.issue | 2 | - |
dc.identifier.doi | 10.1002/anie.202012133 | en_US |
dcterms.abstract | Chirality is ubiquitous within biological systems where many of the roles and functions are still undetermined. Given this, there is a clear need to design and develop sensitive chiral optical probes that can function within a biological setting. Here we report the design and synthesis of magnetically responsive Circularly Polarized Luminescence (CPL) complexes displaying exceptional photophysical properties (quantum yield up to 31 % and |g(lum)| up to 0.240) by introducing chiral substituents onto the macrocyclic scaffolds. Magnetic CPL responses are observed in these chiral Eu-III complexes, promoting an exciting development to the field of magneto-optics. The |g(lum)| of the D-5(0) -> F-7(1) transition increases by 20 % from 0.222 (0 T) to 0.266 (1.4 T) displaying a linear relationship between the Delta g(lum) and the magnetic field strength. These Eu-III complexes with magnetic CPL responses, provides potential development to be used in CPL imaging applications due to improved sensitivity and resolution. | - |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Angewandte chemie international edition, Jan. 2021, v. 60, no. 2, p. 1004-1010 | - |
dcterms.isPartOf | Angewandte chemie international edition | en_US |
dcterms.issued | 2021-01 | - |
dc.identifier.isi | WOS:000584116300001 | - |
dc.identifier.scopus | 2-s2.0-85096675415 | - |
dc.identifier.pmid | 32959961 | - |
dc.identifier.eissn | 1521-3773 | en_US |
dc.description.validate | 202012 bcrc | - |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_Scopus/WOS | en_US |
dc.description.pubStatus | Published | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Zhang_Unusual_Magnetic_Field.pdf | 1.72 MB | Adobe PDF | View/Open |
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