Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/96183
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | en_US |
dc.creator | Lu, YS | en_US |
dc.creator | Yu, WY | en_US |
dc.date.accessioned | 2022-11-11T07:56:53Z | - |
dc.date.available | 2022-11-11T07:56:53Z | - |
dc.identifier.issn | 1523-7060 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/96183 | - |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | © 2016 American Chemical Society | en_US |
dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.6b00283. | en_US |
dc.title | Cp*Rh(III)-catalyzed cross-coupling of alkyltrifluoroborate with α-diazomalonates for C(sp³)-C(sp³) bond formation | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 1350 | en_US |
dc.identifier.epage | 1353 | en_US |
dc.identifier.volume | 18 | en_US |
dc.identifier.issue | 6 | en_US |
dc.identifier.doi | 10.1021/acs.orglett.6b00283 | en_US |
dcterms.abstract | A Cp∗Rh(III)-catalyzed cross-coupling of alkyltrifluoroborate with α-diazomalonates was developed; the C(sp³)-C(sp³) bond coupled products were formed in up to 97% yields. The reaction tolerates some useful functional groups, including ketone, ester, amide, ether, sulfonyl, and thiophene. Electrospray ionization mass spectrometry (ESI-MS) analysis revealed the formation of a distinct molecular species corresponding to σ-alkylrhodium(III) complexes. The successful diazo coupling reaction may be attributed to coordination of the amide group that promotes stability of the alkylrhodium(III) complex through the formation of a five-membered metallacycle. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Organic letters, 18 Mar. 2016, v. 18, no. 6, p. 1350-1353 | en_US |
dcterms.isPartOf | Organic letters | en_US |
dcterms.issued | 2016-03-18 | - |
dc.identifier.scopus | 2-s2.0-84961859406 | - |
dc.identifier.eissn | 1523-7052 | en_US |
dc.description.validate | 202211 bckw | en_US |
dc.description.oa | Accepted Manuscript | en_US |
dc.identifier.FolderNumber | RGC-B3-0059, ABCT-0779 | - |
dc.description.fundingSource | RGC | en_US |
dc.description.pubStatus | Published | en_US |
dc.identifier.OPUS | 6630001 | - |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
CpRhIII-Catalyzed_Cross-Coupling_Alkyltrifluoroborate.pdf | Pre-Published version | 817.36 kB | Adobe PDF | View/Open |
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