Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/95307
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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorFu, WCen_US
dc.creatorWang, Zen_US
dc.creatorChan, WTKen_US
dc.creatorLin, Zen_US
dc.creatorKwong, FYen_US
dc.date.accessioned2022-09-14T08:33:05Z-
dc.date.available2022-09-14T08:33:05Z-
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10397/95307-
dc.language.isoenen_US
dc.publisherWiley-VCHen_US
dc.rights© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.rightsThis is the peer reviewed version of the following article: W. C. Fu, Z. Wang, W. T. K. Chan, Z. Lin, F. Y. Kwong, Regioselective Synthesis of Polycyclic and Heptagon-embedded Aromatic Compounds through a Versatile π-Extension of Aryl Halides, Angew. Chem. Int. Ed. 2017, 56, 7166, which has been published in final form at https://doi.org/10.1002/anie.201703551. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.en_US
dc.subjectCross-couplingen_US
dc.subjectC−H functionalizationen_US
dc.subjectDecarboxylationen_US
dc.subjectPalladiumen_US
dc.subjectPolycyclic aromatic hydrocarbonsen_US
dc.titleRegioselective synthesis of polycyclic and heptagon-embedded aromatic compounds through a versatile π-extension of aryl halidesen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage7166en_US
dc.identifier.epage7170en_US
dc.identifier.volume56en_US
dc.identifier.issue25en_US
dc.identifier.doi10.1002/anie.201703551en_US
dcterms.abstractA versatile π-extension reaction was developed based on the three-component cross-coupling of aryl halides, 2-haloarylcarboxylic acids, and norbornadiene. The transformation is driven by the direction and subsequent decarboxylation of the carboxyl group, while norbornadiene serves as an ortho-C−H activator and ethylene synthon via a retro-Diels–Alder reaction. Comprehensive DFT calculations were performed to account for the catalytic intermediates.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationAngewandte chemie international edition, 12 June 2017, v. 56, no. 25, p. 7166-7170en_US
dcterms.isPartOfAngewandte chemie international editionen_US
dcterms.issued2017-06-12-
dc.identifier.scopus2-s2.0-85019481217-
dc.identifier.pmid28510348-
dc.identifier.eissn1521-3773en_US
dc.description.validate202209 bckwen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberRGC-B2-1525, ABCT-0644en_US
dc.description.fundingSourceRGCen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS54688497en_US
dc.description.oaCategoryGreen (AAM)en_US
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