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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorFu, WCen_US
dc.creatorZheng, Ben_US
dc.creatorZhao, Qen_US
dc.creatorChan, WTKen_US
dc.creatorKwong, FYen_US
dc.date.accessioned2022-09-14T08:33:04Z-
dc.date.available2022-09-14T08:33:04Z-
dc.identifier.issn1523-7060en_US
dc.identifier.urihttp://hdl.handle.net/10397/95305-
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2017 American Chemical Societyen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.orglett.7b02023.en_US
dc.titleCascade amination and acetone monoarylation with aryl iodides by palladium/norbornene cooperative catalysisen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage4335en_US
dc.identifier.epage4338en_US
dc.identifier.volume19en_US
dc.identifier.issue16en_US
dc.identifier.doi10.1021/acs.orglett.7b02023en_US
dcterms.abstractA palladium/norbornene cocatalyzed three-component reaction of aryl iodides, O-benzoylhydroxylamines, and acetone is reported. o′-Aminoaryl acetones or o,o′-diaminoaryl acetones are efficiently prepared via tandem ortho-C-H amination/ipso-C-I α-arylation sequence, and the regiospecificity has been confirmed by X-ray analysis. The proposed method addresses the condensation/amination of free-N-H-bearing substrates in acetone monoarylations and the synthesis of extremely congested 2,6-disubstituted aryl acetones.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationOrganic letters, 18 Aug. 2017, v. 19, no. 16, p. 4335-4338en_US
dcterms.isPartOfOrganic lettersen_US
dcterms.issued2017-08-18-
dc.identifier.scopus2-s2.0-85027566096-
dc.identifier.pmid28758754-
dc.identifier.eissn1523-7052en_US
dc.description.validate202209 bckwen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberRGC-B2-1526, ABCT-0627-
dc.description.fundingSourceRGCen_US
dc.description.fundingSourceOthersen_US
dc.description.fundingTextNational Natural Science Foundation of Chinaen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS54688943-
dc.description.oaCategoryGreen (AAM)en_US
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