Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/81223
DC Field | Value | Language |
---|---|---|
dc.contributor | Chinese Mainland Affairs Office | - |
dc.contributor | Department of Applied Biology and Chemical Technology | - |
dc.creator | Yeung, CT | - |
dc.creator | Chan, WTK | - |
dc.creator | Lo, WS | - |
dc.creator | Law, GL | - |
dc.creator | Wong, WT | - |
dc.date.accessioned | 2019-08-23T08:29:48Z | - |
dc.date.available | 2019-08-23T08:29:48Z | - |
dc.identifier.uri | http://hdl.handle.net/10397/81223 | - |
dc.language.iso | en | en_US |
dc.publisher | Beilstein-Institut Zur Forderung der Chemischen Wissenschaften | en_US |
dc.rights | © 2019 Yeung et al. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. | en_US |
dc.rights | The following publication Yeung, C.-T.; Chan, W. T. K.; Lo, W.-S.; Law, G.-L.; Wong, W.-T. Beilstein J. Org. Chem. 2019, 15, 955–962 is available at https://doi.org/10.3762/bjoc.15.92 | en_US |
dc.subject | Asymmetric organocatalysis | en_US |
dc.subject | Axial chirality | en_US |
dc.subject | Biaryls | en_US |
dc.subject | Hydrogen bond | en_US |
dc.subject | Oxo-Diels-Alder reaction | en_US |
dc.title | Catalytic asymmetric oxo-Diels-Alder reactions with chiral atropisomeric biphenyl diols | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 955 | - |
dc.identifier.epage | 962 | - |
dc.identifier.volume | 15 | - |
dc.identifier.doi | 10.3762/bjoc.15.92 | - |
dcterms.abstract | New chiral atropisomeric biphenyl diols 3, 4 and 6 containing additional peripheral chiral centers with different steric bulkiness and/or electronic properties were synthesized. The X-ray crystal structure of 3 shows the formation of a supramolecular structure whereas that of 6, containing additional CF3 substituents, shows the formation of a monomeric structure. Diols 1-6 were found to be active organocatalysts in oxo-Diels-Alder reactions in which 2 recorded a 72% ee with trimethylacetaldehyde as a substrate. | - |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Beilstein journal of nanotechnology, 2019, v. 15, p. 955-962 | - |
dcterms.isPartOf | Beilstein journal of nanotechnology | - |
dcterms.issued | 2019 | - |
dc.identifier.scopus | 2-s2.0-85066476319 | - |
dc.identifier.eissn | 1860-5397 | - |
dc.description.validate | 201908 bcma | - |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_Scopus/WOS | en_US |
dc.description.pubStatus | Published | en_US |
dc.description.oaCategory | CC | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
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Yeung_Catalytic_asymmetric_oxo-Diels-Alder.pdf | 767.78 kB | Adobe PDF | View/Open |
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