Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/81223
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dc.contributorChinese Mainland Affairs Office-
dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorYeung, CT-
dc.creatorChan, WTK-
dc.creatorLo, WS-
dc.creatorLaw, GL-
dc.creatorWong, WT-
dc.date.accessioned2019-08-23T08:29:48Z-
dc.date.available2019-08-23T08:29:48Z-
dc.identifier.urihttp://hdl.handle.net/10397/81223-
dc.language.isoenen_US
dc.publisherBeilstein-Institut Zur Forderung der Chemischen Wissenschaftenen_US
dc.rights© 2019 Yeung et al. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited.en_US
dc.rightsThe following publication Yeung, C.-T.; Chan, W. T. K.; Lo, W.-S.; Law, G.-L.; Wong, W.-T. Beilstein J. Org. Chem. 2019, 15, 955–962 is available at https://doi.org/10.3762/bjoc.15.92en_US
dc.subjectAsymmetric organocatalysisen_US
dc.subjectAxial chiralityen_US
dc.subjectBiarylsen_US
dc.subjectHydrogen bonden_US
dc.subjectOxo-Diels-Alder reactionen_US
dc.titleCatalytic asymmetric oxo-Diels-Alder reactions with chiral atropisomeric biphenyl diolsen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage955-
dc.identifier.epage962-
dc.identifier.volume15-
dc.identifier.doi10.3762/bjoc.15.92-
dcterms.abstractNew chiral atropisomeric biphenyl diols 3, 4 and 6 containing additional peripheral chiral centers with different steric bulkiness and/or electronic properties were synthesized. The X-ray crystal structure of 3 shows the formation of a supramolecular structure whereas that of 6, containing additional CF3 substituents, shows the formation of a monomeric structure. Diols 1-6 were found to be active organocatalysts in oxo-Diels-Alder reactions in which 2 recorded a 72% ee with trimethylacetaldehyde as a substrate.-
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationBeilstein journal of nanotechnology, 2019, v. 15, p. 955-962-
dcterms.isPartOfBeilstein journal of nanotechnology-
dcterms.issued2019-
dc.identifier.scopus2-s2.0-85066476319-
dc.identifier.eissn1860-5397-
dc.description.validate201908 bcma-
dc.description.oaVersion of Recorden_US
dc.identifier.FolderNumberOA_Scopus/WOSen_US
dc.description.pubStatusPublisheden_US
dc.description.oaCategoryCCen_US
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