Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/80655
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dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorWong, HY-
dc.creatorChan, TKW-
dc.creatorLaw, GL-
dc.date.accessioned2019-04-23T08:16:45Z-
dc.date.available2019-04-23T08:16:45Z-
dc.identifier.issn1420-3049en_US
dc.identifier.urihttp://hdl.handle.net/10397/80655-
dc.language.isoenen_US
dc.publisherMolecular Diversity Preservation International (MDPI)en_US
dc.rights© 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).en_US
dc.rightsThe following publication Wong, H. Y., Chan, W. T. K., & Law, G. L. (2019). Triboluminescence of Centrosymmetric Lanthanide β-Diketonate Complexes with Aggregation-Induced Emission. Molecules, 24(4), 662 is available at https://doi.org/10.3390/molecules24040662en_US
dc.subjectLanthanideen_US
dc.subjectTriboluminescenceen_US
dc.subjectβ-diketonateen_US
dc.titleTriboluminescence of centrosymmetric lanthanide β-diketonate complexes with aggregation-induced emissionen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.volume24en_US
dc.identifier.issue4en_US
dc.identifier.doi10.3390/molecules24040662en_US
dcterms.abstractTriboluminescence (TL) is a form of light emission induced upon mechanical forces on the material. However, our understanding of this phenomenon is still unclear and more examples are therefore needed in order to elucidate its mechanism. In this work, two types of TL complexes, [Eu(pp-dbm-Cl 2 ) 3 phen] and [Eu(mm-dbm-Cl 2 ) 3 phen], which also displays aggregation-induced emission (AIE) were synthesized and investigated for its photo-physical and crystal structural properties. These complexes were crystallized in a centro-symmetric space group P2 1 /n, and remarkably, displayed TL upon grinding that may be due to the presence of extensive π···π, C-H···π and C-H···Cl-C interactions in the close molecular packing of its structure. This rare example deviates from the widely accepted mechanism of TL, hence widening the scope of our understanding in the area.-
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationMolecules, 2019, v. 24, no. 4, 662-
dcterms.isPartOfMolecules-
dcterms.issued2019-
dc.identifier.scopus2-s2.0-85061634480-
dc.identifier.pmid30781832-
dc.identifier.artn662en_US
dc.description.validate201904 bcmaen_US
dc.description.oaVersion of Recorden_US
dc.identifier.FolderNumberOA_IR/PIRAen_US
dc.description.pubStatusPublisheden_US
dc.description.oaCategoryCCen_US
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