Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/66095
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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorCui, JFen_US
dc.creatorKo, HMen_US
dc.creatorShing, KPen_US
dc.creatorDeng, Jen_US
dc.creatorLai, CHNen_US
dc.creatorWong, MKen_US
dc.date.accessioned2017-05-22T02:09:40Z-
dc.date.available2017-05-22T02:09:40Z-
dc.identifier.issn1433-7851en_US
dc.identifier.urihttp://hdl.handle.net/10397/66095-
dc.language.isoenen_US
dc.publisherWiley-VCHen_US
dc.rights© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.rightsThis is the peer reviewed version of the following article: J.-F. Cui, H.-M. Ko, K.-P. Shing, J.-R. Deng, N. C.-H. Lai, M.-K. Wong, Angew. Chem. Int. Ed. 2017, 56, 3074, which has been published in final form at https://doi.org/10.1002/anie.201612243. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.en_US
dc.subjectChelatesen_US
dc.subjectGolden_US
dc.subjectIsomerizationen_US
dc.subjectLigand effectsen_US
dc.subjectStructure elucidationen_US
dc.titleC,O-Chelated BINOL/Gold(III) complexes : synthesis and catalysis with tunable product profilesen_US
dc.typeJournal/Magazine Articleen_US
dc.description.otherinformationTitle on author’s file: Unprecedented C,O-Chelated BINOL-Gold(III) complexes : synthesis and catalysis with tunable product profilesen_US
dc.identifier.spage3074en_US
dc.identifier.epage3079en_US
dc.identifier.volume56en_US
dc.identifier.issue11en_US
dc.identifier.doi10.1002/anie.201612243en_US
dcterms.abstractUnprecedented stable BINOL/gold(III) complexes, adopting a novel C,O-chelation mode, were synthesized by a modular approach through combination of 1,1′-binaphthalene-2,2′-diols (BINOLs) and cyclometalated gold(III) dichloride complexes [(C^N)AuCl2]. X-ray crystallographic analysis revealed that the bidentate BINOL ligands tautomerized and bonded to the AuIII atom through C,O-chelation to form a five-membered ring instead of the conventional O,O′-chelation giving a seven-membered ring. These gold(III) complexes catalyzed acetalization/cycloisomerization and carboalkoxylation of ortho-alkynylbenzaldehydes with trialkyl orthoformates.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationAngewandte chemie international edition, 6 Mar. 2017, v. 56, no. 11, p. 3074-3079en_US
dcterms.isPartOfAngewandte chemie international editionen_US
dcterms.issued2017-03-06-
dc.identifier.scopus2-s2.0-85012053034-
dc.identifier.ros2016001426-
dc.identifier.eissn1521-3773en_US
dc.identifier.rosgroupid2016001400-
dc.description.ros2016-2017 > Academic research: refereed > Publication in refereed journalen_US
dc.description.validate201804_a bcmaen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumbera0589-n12-
dc.identifier.SubFormID319-
dc.description.fundingSourceRGCen_US
dc.description.fundingTextPolyU 153006/15Pen_US
dc.description.pubStatusPublisheden_US
dc.description.oaCategoryGreen (AAM)en_US
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