Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/66095
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | en_US |
dc.creator | Cui, JF | en_US |
dc.creator | Ko, HM | en_US |
dc.creator | Shing, KP | en_US |
dc.creator | Deng, J | en_US |
dc.creator | Lai, CHN | en_US |
dc.creator | Wong, MK | en_US |
dc.date.accessioned | 2017-05-22T02:09:40Z | - |
dc.date.available | 2017-05-22T02:09:40Z | - |
dc.identifier.issn | 1433-7851 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/66095 | - |
dc.language.iso | en | en_US |
dc.publisher | Wiley-VCH | en_US |
dc.rights | © 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim | en_US |
dc.rights | This is the peer reviewed version of the following article: J.-F. Cui, H.-M. Ko, K.-P. Shing, J.-R. Deng, N. C.-H. Lai, M.-K. Wong, Angew. Chem. Int. Ed. 2017, 56, 3074, which has been published in final form at https://doi.org/10.1002/anie.201612243. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. | en_US |
dc.subject | Chelates | en_US |
dc.subject | Gold | en_US |
dc.subject | Isomerization | en_US |
dc.subject | Ligand effects | en_US |
dc.subject | Structure elucidation | en_US |
dc.title | C,O-Chelated BINOL/Gold(III) complexes : synthesis and catalysis with tunable product profiles | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.description.otherinformation | Title on author’s file: Unprecedented C,O-Chelated BINOL-Gold(III) complexes : synthesis and catalysis with tunable product profiles | en_US |
dc.identifier.spage | 3074 | en_US |
dc.identifier.epage | 3079 | en_US |
dc.identifier.volume | 56 | en_US |
dc.identifier.issue | 11 | en_US |
dc.identifier.doi | 10.1002/anie.201612243 | en_US |
dcterms.abstract | Unprecedented stable BINOL/gold(III) complexes, adopting a novel C,O-chelation mode, were synthesized by a modular approach through combination of 1,1′-binaphthalene-2,2′-diols (BINOLs) and cyclometalated gold(III) dichloride complexes [(C^N)AuCl2]. X-ray crystallographic analysis revealed that the bidentate BINOL ligands tautomerized and bonded to the AuIII atom through C,O-chelation to form a five-membered ring instead of the conventional O,O′-chelation giving a seven-membered ring. These gold(III) complexes catalyzed acetalization/cycloisomerization and carboalkoxylation of ortho-alkynylbenzaldehydes with trialkyl orthoformates. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Angewandte chemie international edition, 6 Mar. 2017, v. 56, no. 11, p. 3074-3079 | en_US |
dcterms.isPartOf | Angewandte chemie international edition | en_US |
dcterms.issued | 2017-03-06 | - |
dc.identifier.scopus | 2-s2.0-85012053034 | - |
dc.identifier.ros | 2016001426 | - |
dc.identifier.eissn | 1521-3773 | en_US |
dc.identifier.rosgroupid | 2016001400 | - |
dc.description.ros | 2016-2017 > Academic research: refereed > Publication in refereed journal | en_US |
dc.description.validate | 201804_a bcma | en_US |
dc.description.oa | Accepted Manuscript | en_US |
dc.identifier.FolderNumber | a0589-n12 | - |
dc.identifier.SubFormID | 319 | - |
dc.description.fundingSource | RGC | en_US |
dc.description.fundingText | PolyU 153006/15P | en_US |
dc.description.pubStatus | Published | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
a0589-n12_Manuscript (2).pdf | Pre-Published version | 1.06 MB | Adobe PDF | View/Open |
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