Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/5105
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dc.contributorDepartment of Applied Biology and Chemical Technology-
dc.creatorGöthe, MC-
dc.creatorWannberg, B-
dc.creatorKarlsson, L-
dc.creatorSvensson, S-
dc.creatorBaltzer, P-
dc.creatorChau, FT-
dc.creatorAdam, MY-
dc.date.accessioned2014-12-11T08:29:03Z-
dc.date.available2014-12-11T08:29:03Z-
dc.identifier.issn0021-9606-
dc.identifier.urihttp://hdl.handle.net/10397/5105-
dc.language.isoenen_US
dc.publisherAmerican Institute of Physicsen_US
dc.rights© 1991 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in M. C. Göthe et al., J. Chem. Phys. 94, 2536 (1991) and may be found at http://link.aip.org/link/?jcp/94/2536.en_US
dc.subjectSynchrotron radiationen_US
dc.subjectX radiationen_US
dc.subjectUltraviolet radiationen_US
dc.subjectInner−shell excitationen_US
dc.subjectPhotoelectron spectroscopyen_US
dc.subjectMethaneen_US
dc.subjectBond lengthsen_US
dc.subjectFranck−condon principleen_US
dc.subjectLine widthsen_US
dc.subjectVibrational statesen_US
dc.subjectValenceen_US
dc.titleX-ray, ultraviolet, and synchrotron radiation excited inner-valence photoelectron spectra of CH₄en_US
dc.typeJournal/Magazine Articleen_US
dc.description.otherinformationAuthor name used in this publication: F. T. Chauen_US
dc.identifier.spage2536-
dc.identifier.epage2542-
dc.identifier.volume94-
dc.identifier.issue4-
dc.identifier.doi10.1063/1.459880-
dcterms.abstractThe inner-valence electron states of the methane molecule have been studied by means of x-ray, synchrotron radiation, and UV-photoelectron spectroscopy. Five correlation satellites have been identified and a detailed study has been carried out of the 2a₁⁻¹ single hole state. For this state a Franck-Condon analysis has been performed, suggesting an equilibrium bond distance of 1.279 Å. The vibrational lines have a Lorentzian shape and the linewidth increases gradually with the vibrational quantum number. This probably indicates a reduction of the lifetime of the vibrational states due to predissociation. A discussion of the potential curves related to the correlation satellites is included.-
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationJournal of chemical physics, 15 Feb. 1991, v. 94, no. 4, p. 2536-2542-
dcterms.isPartOfJournal of chemical physics-
dcterms.issued1991-02-15-
dc.identifier.isiWOS:A1991EY07000020-
dc.identifier.scopus2-s2.0-33749473703-
dc.identifier.eissn1089-7690-
dc.description.oaVersion of Recorden_US
dc.identifier.FolderNumberOA_IR/PIRAen_US
dc.description.pubStatusPublisheden_US
dc.description.oaCategoryVoR alloweden_US
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