Experimental study of alkali-activated cementitious materials using thermally activated red mud : effect of the Si/Al ratio on fresh and mechanical properties

Abstract

Bayer red mud (RM)-based geopolymers are economical and ecofriendly alternatives to cement because of their superior performance. This study investigated alkali-activated cementitious materials by combining RM, fly ash (FA) and slag, and the mixtures were used to produce ecofriendly composites. The influence of the Si/Al molar ratio (3.30–3.79) on the initial properties (setting time and flowability) and hardened properties (compressive strength, drying shrinkage and water permeability) of the composite materials was studied. The Na2O content was fixed at 4 wt%, and the thermal activation temperature was 800 °C. The phase evolution and geopolymerization mechanism of the effect of the initial Si/Al molar ratio on the material properties was investigated by FTIR, XRD, TG–DTG and SEM–EDS. The results of M1.2Si333 indicated that the compressive strength of the blends can reach 33.5 MPa at 28 days, with a drying shrinkage rate of 1.20%. Compressive strength decreases, while drying shrinkage increases with a higher initial Si/Al ratio. Microstructural analyses revealed that a low Si/Al ratio and alkali activator modulus enhance the dissolution of precursors to form C–(A)–S–H gels, which increase the compressive strength. The results promoted the application of RM-based geopolymer-engineered cementitious composite and enhanced the resource efficiency of the bauxite residue.