Hydroxyl dicarboxylic acids at a mountainous site in Hong Kong : formation mechanisms and implications for particle growth

Abstract

Secondary organic aerosol (SOA) has been shown to significantly impact climate, air quality, and human health. Hydroxyl dicarboxylic acids (OHDCA) are generally of secondary origin and ubiquitous in the atmosphere, with high concentrations in South China. This study explored the formation of representative OHDCA species based on time-resolved measurements and explainable machine learning. Malic acid, the most commonly studied OHDCA, had higher concentrations in the noncontinental air (63.7 ± 33.3 ng m-3) than in the continental air (7.5 ± 1.4 ng m-3). Machine learning quantitatively revealed the high relative importance of aromatics and monoterpenes SOA, as well as aqueous processes, in the noncontinental air, due to either shared precursors or similar formation pathways. Isoprene SOA, particle surface area, and ozone corrected for titration loss (Ox) also elevated the concentrations of malic acid in the continental air. Aqueous photochemical formation of malic acid was confirmed given the synergy between LWC, temperature, and Ox. Moreover, the OHDCA-like SOA might have facilitated a relatively rare particle growth from early afternoon to midnight in the case with the highest malic acid concentrations. This study enhances our understanding of the formation of OHDCA and its climate impacts.