Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/117332
DC FieldValueLanguage
dc.contributorMainland Development Officeen_US
dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorLai, LYen_US
dc.creatorLau, PCen_US
dc.creatorKwong, TLen_US
dc.creatorYung, KFen_US
dc.date.accessioned2026-02-12T01:38:04Z-
dc.date.available2026-02-12T01:38:04Z-
dc.identifier.issn0022-328Xen_US
dc.identifier.urihttp://hdl.handle.net/10397/117332-
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.subjectEnergyen_US
dc.subjectGlycerol carbonateen_US
dc.subjectGlycidolen_US
dc.subjectIron (III) salen complexen_US
dc.subjectSalen complexen_US
dc.subjectTransesterificationen_US
dc.titleTransesterification of glycerol with dimethyl carbonate for the synthesis of glycerol carbonate and glycidol by iron (III) salen complexen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.volume1025en_US
dc.identifier.doi10.1016/j.jorganchem.2024.123467en_US
dcterms.abstractThe transesterification of glycerol and dimethyl carbonate (DMC) was investigated in the presence of μ-oxo-Fe(salen)<inf>2</inf> under the optimal reaction condition. Several transition metal(salen) were tested, and only Fe (salen) shows an excellent results towards transesterification of glycerol. Therefore, Fe (salen) was characterized by IR, elemental analysis, MS, XPS and Surface Basicity test, and it can be confirmed that the as-synthesized Fe(salen) was existed in the form of μ-oxo-Fe(salen)<inf>2</inf>. It was proposed that the μ-oxo-Fe(salen)<inf>2</inf> can provide two different reaction pathway based on its molecular structures and the electronic configuration of iron itself. μ-oxo-Fe(salen)<inf>2</inf> was reacted with the mixture of glycerol and DMC under microwave-heating in 60 min at 100 °C and at the molar ratio of glycerol:DMC:μ-oxo-Fe(salen)<inf>2</inf> of 1:2:0.01 and obtaining the highest glycerol carbonate yield of 93.8 %.en_US
dcterms.accessRightsembargoed accessen_US
dcterms.bibliographicCitationJournal of organometallic chemistry, 1 Feb. 2025, v. 1025, 123467en_US
dcterms.isPartOfJournal of organometallic chemistryen_US
dcterms.issued2025-02-01-
dc.identifier.scopus2-s2.0-85212561471-
dc.identifier.artn123467en_US
dc.description.validate202602 bchyen_US
dc.description.oaNot applicableen_US
dc.identifier.SubFormIDG000914/2025-12-
dc.description.fundingSourceOthersen_US
dc.description.fundingTextThe authors would like to acknowledge the financial support from The Hong Kong Polytechnic University with grant numbers PolyU P0039669 and Environment and Conservation Fund with the grant numbers of ECF88/2021 . The authors are also very grateful to thank the University Research Facility in Chemical and Environmental Analysis (UCEA) of The Hong Kong Polytechnic University for supporting the analytical instruments used in this research study. Also, the authors are also appreciate The Hong Kong Polytechnic University for supporting the research stipend funding for Mr. Long-Yat LAI.en_US
dc.description.pubStatusPublisheden_US
dc.date.embargo2027-02-01en_US
dc.description.oaCategoryGreen (AAM)en_US
Appears in Collections:Journal/Magazine Article
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Embargo End Date 2027-02-01
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