Multitrack boosted hard carbon anodes : innovative paths and advanced performances in sodium-ion batteries

Abstract

Sodium-ion batteries (SIBs) are emerging as a potential alternative to traditional lithium-ion batteries due to the abundant sodium resources. Carbon anodes, with their stable structure, wide availability, low cost, excellent conductivity, and tunable morphology and pore structure, exhibit outstanding performance in SIBs. This review summarizes the research progress of hard carbon anodes in SIBs, emphasizing the innovative paths and advanced performances achieved through multitrack optimization, including dimensional engineering, heteroatom doping, and microstructural tailoring. Each dimension of carbon material—0D, 1D, 2D, and 3D—offers unique advantages: 0D materials ensure uniform dispersion, 1D materials have short Na+ diffusion paths, 2D materials possess large specific surface areas, and 3D materials provide e−/Na+ conductive networks. Heteroatom doping with elements such as N, S, and P can tune electronic distribution, expand interlayer spacing of carbon, and induce Fermi level shifts, thereby enhancing sodium storage capability. In addition, defect engineering improves electrochemical performance by modifying graphitic crystal structure. Furthermore, suitable pore structure design, particularly closed pore structures, can increase capacity, minimizes side reactions, and suppress degradation. In future studies, optimizing morphology design, exploring heteroatom co-doping, and developing environmentally friendly, low-cost carbon anode methods will drive the application of high-performance and long cycle life SIBs.