Study of factors affecting UV-induced photo-degradation in different types of polyethylene sheets

Abstract

Enhancing the degradability of polyethylene plastics could provide a potential solution to the overwhelming crisis of plastic waste. Conventional studies have focused on the degradation of polyethylene thin films. This study investigated UV-induced photo-degradation according to ASTM D5208-14 in polyethylene sheets with thicknesses ranging from 0.4 to 1.2 mm. The impacts of sample thickness, metal pro-oxidants, polyethylene resin types and foaming were explored through the characterization of the carbonyl index, molecular weight, tensile properties and crystallinity. As pro-oxidants, single iron or manganese stearate demonstrated a concentration-dependent trend in accelerating the photo-degradation of polyethylene sheets. The thickness, foaming and resin type—such as low-density polyethylene (LDPE) and high-density polyethylene (HDPE)—significantly impacted the rate of photo-oxidation. Thick polyethylene sheets (1.2 mm) exhibited a heterogenous and depth-dependent degradation profile. As the photo-degradation progressed, the enhanced crystallinity, reduced UV transmittance and formation of crosslinks were able to prevent further oxidative cleavage of the polyethylene chain. This study investigated the time course and factors affecting the photo-degradation of polyethylene sheets, which could provide insights into the formulation design of photo-degradable polyethylene plastics.