Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/106063
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Mechanical Engineering | en_US |
dc.contributor | Research Institute for Smart Energy | en_US |
dc.creator | Xie, C | en_US |
dc.creator | Zhao, C | en_US |
dc.creator | Jeong, H | en_US |
dc.creator | Li, T | en_US |
dc.creator | Li, L | en_US |
dc.creator | Xu, W | en_US |
dc.creator | Yang, Z | en_US |
dc.creator | Lin, C | en_US |
dc.creator | Liu, Q | en_US |
dc.creator | Cheng, L | en_US |
dc.creator | Huang, X | en_US |
dc.creator | Xu, GL | en_US |
dc.creator | Amine, K | en_US |
dc.creator | Chen, G | en_US |
dc.date.accessioned | 2024-05-02T08:30:52Z | - |
dc.date.available | 2024-05-02T08:30:52Z | - |
dc.identifier.issn | 1433-7851 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/106063 | - |
dc.language.iso | en | en_US |
dc.publisher | Wiley-VCH | en_US |
dc.rights | © 2023 The Authors. Published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial License (https://creativecommons.org/licenses/by-nc/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes. | en_US |
dc.rights | The following publication Xie, C., Zhao, C., Jeong, H., Li, T., Li, L., Xu, W., ... & Chen, G. (2023). Suppressing Universal Cathode Crossover in High‐Energy Lithium Metal Batteries via a Versatile Interlayer Design. Angewandte Chemie, 135(19), e202217476 is available at https://doi.org/10.1002/anie.202217476. | en_US |
dc.subject | Cathode Cross-over | en_US |
dc.subject | High-Energy Cathode | en_US |
dc.subject | Lithium-Metal Batteries | en_US |
dc.subject | Solid-Electrolyte Interphase | en_US |
dc.title | Suppressing universal cathode crossover in high-energy lithium metal batteries via a versatile interlayer design | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.volume | 62 | en_US |
dc.identifier.issue | 19 | en_US |
dc.identifier.doi | 10.1002/anie.202217476 | en_US |
dcterms.abstract | The universal cathode crossover such as chemical and oxygen has been significantly overlooked in lithium metal batteries using high-energy cathodes which leads to severe capacity degradation and raises serious safety concerns. Herein, a versatile and thin (≈25 μm) interlayer composed of multifunctional active sites was developed to simultaneously regulate the Li deposition process and suppress the cathode crossover. The as-induced dual-gradient solid-electrolyte interphase combined with abundant lithiophilic sites enable stable Li stripping/plating process even under high current density of 10 mA cm−2. Moreover, X-ray photoelectron spectroscopy and synchrotron X-ray experiments revealed that N-rich framework and CoZn dual active sites can effectively mitigate the undesired cathode crossover, hence significantly minimizing Li corrosion. Therefore, assembled lithium metal cells using various high-energy cathode materials including LiNi0.7Mn0.2Co0.1O2, Li1.2Co0.1Mn0.55Ni0.15O2, and sulfur demonstrate significantly improved cycling stability with high cathode loading. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Angewandte chemie international edition, 2 May 2023, v. 62, no. 19, e202217476 | en_US |
dcterms.isPartOf | Angewandte chemie international edition | en_US |
dcterms.issued | 2023-05-02 | - |
dc.identifier.scopus | 2-s2.0-85151461559 | - |
dc.identifier.pmid | 36917790 | - |
dc.identifier.eissn | 1521-3773 | en_US |
dc.identifier.artn | e202217476 | en_US |
dc.description.validate | 202404 bcwh | en_US |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_Others | - |
dc.description.fundingSource | Others | en_US |
dc.description.fundingText | Shenzhen Science and Technology Program; the Guangdong Basic and Applied Basic Research Foundation; GDSTC-Guangdong-HK-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices | en_US |
dc.description.pubStatus | Published | en_US |
dc.description.oaCategory | CC | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Xie_Suppressing_Universal_Cathode .pdf | 6.28 MB | Adobe PDF | View/Open |
Page views
9
Citations as of Jun 30, 2024
Downloads
1
Citations as of Jun 30, 2024
SCOPUSTM
Citations
6
Citations as of Jul 4, 2024
WEB OF SCIENCETM
Citations
5
Citations as of Jul 4, 2024
![](/image/google_scholar.jpg)
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.