Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/106061
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | en_US |
dc.contributor | Research Institute for Smart Energy | en_US |
dc.creator | Bodedla, GB | en_US |
dc.creator | Imran, M | en_US |
dc.creator | Zhao, J | en_US |
dc.creator | Zhu, X | en_US |
dc.creator | Wong, WY | en_US |
dc.date.accessioned | 2024-05-02T08:30:51Z | - |
dc.date.available | 2024-05-02T08:30:51Z | - |
dc.identifier.issn | 2766-8541 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/106061 | - |
dc.language.iso | en | en_US |
dc.publisher | John Wiley & Sons, Inc. | en_US |
dc.rights | © 2023 The Authors. Aggregate published by SCUT, AIEI, and John Wiley & Sons Australia, Ltd. | en_US |
dc.rights | This is an open access article under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by-nc/4.0/), which permits use, distribution and reproduction in any medium, provided the original work is properly cited. | en_US |
dc.rights | The following publication Bodedla, G. B., Imran, M., Zhao, J., Zhu, X., & Wong, W. Y. (2023). Design of AIEgen‐based porphyrin for efficient heterogeneous photocatalytic hydrogen evolution: Special Collection: Aggregation‐Induced Processes and Functions. Aggregate, 4(5), e364 is available at https://doi.org/10.1002/agt2.364. | en_US |
dc.subject | Aggregation-induced emission | en_US |
dc.subject | AIEgen | en_US |
dc.subject | Photocatalytic hydrogen evolution | en_US |
dc.subject | Porphyrin | en_US |
dc.subject | Π-π-stacking | en_US |
dc.title | Design of AIEgen-based porphyrin for efficient heterogeneous photocatalytic hydrogen evolution : special collection : aggregation-induced processes and functions | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.volume | 4 | en_US |
dc.identifier.issue | 5 | en_US |
dc.identifier.doi | 10.1002/agt2.364 | en_US |
dcterms.abstract | Tetraphenylethylene (TPE)-conjugated porphyrin TPE-ZnPF is synthesized in high yield and characterized by single-crystal X-ray diffraction. The propeller-shaped TPE groups not only enable exceptional aggregation-induced emission (AIE) in the solid state but also abolish the strong π-π stacking of porphyrin moieties and thus prohibit aggregation-caused quenching (ACQ). TPE-ZnPF aggregates feature long-lived photoexcited states, which subsequently suppress non-radiative decay channels and enhance emission intensity. Moreover, its aggregates show more efficient light-harvesting ability due to the Förster resonance energy transfer from the TPE energy donor to the porphyrin core energy acceptor, well-defined nanosphere morphology, and more efficient photoinduced charge separation than the porphyrin Ph-ZnPF, which possesses ACQ and agglomerated morphology. As a result, an excellent photocatalytic hydrogen evolution rate (ηH2) of 56.20 mmol g‒1 h‒1 is recorded for TPE-ZnPF aggregates, which is 94-fold higher than that of the aggregates of Ph-ZnPF (0.60 mmol g‒1 h‒1) without the TPE groups. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Aggregate, 2023, v. 4, no. 5, e364 | en_US |
dcterms.isPartOf | Aggregate2692-4560 | en_US |
dcterms.issued | 2023 | - |
dc.identifier.scopus | 2-s2.0-85173543006 | - |
dc.identifier.eissn | 2692-4560 | en_US |
dc.identifier.artn | e364 | en_US |
dc.description.validate | 202404 bcwh | en_US |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_Others | - |
dc.description.fundingSource | RGC | en_US |
dc.description.fundingSource | Others | en_US |
dc.description.fundingText | National Natural Science Foundation of China; the Hong Kong Polytechnic University; Research Institute for Smart Energy; Miss Clarea Au for the Endowed Professorship in Energy; Initiation Grant for Faculty Niche Research Areas from Research Committee of Hong Kong Baptist University | en_US |
dc.description.pubStatus | Published | en_US |
dc.description.oaCategory | CC | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
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Bodedla_Design_AIEgen‐based_Porphyrin.pdf | 1.42 MB | Adobe PDF | View/Open |
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