Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/101612
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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorWong, KCen_US
dc.creatorNg, Een_US
dc.creatorWong, WTen_US
dc.creatorChiu, Pen_US
dc.date.accessioned2023-09-18T07:31:33Z-
dc.date.available2023-09-18T07:31:33Z-
dc.identifier.issn0947-6539en_US
dc.identifier.urihttp://hdl.handle.net/10397/101612-
dc.language.isoenen_US
dc.publisherWiley-VCHen_US
dc.rights© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimen_US
dc.rightsThis is the peer reviewed version of the following article: K. C. Wong, E. Ng, W.-T. Wong, P. Chiu, Copper Hydride Catalyzed Reductive Claisen Rearrangements. Chem. Eur. J. 2016, 22, 3709-3712, which has been published in final form at https://doi.org/10.1002/chem.201504870. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.en_US
dc.subjectClaisen rearrangementsen_US
dc.subjectCopperen_US
dc.subjectHydrideen_US
dc.subjectReductionen_US
dc.subjectSilanesen_US
dc.titleCopper hydride catalyzed reductive Claisen rearrangementsen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage3709en_US
dc.identifier.epage3712en_US
dc.identifier.volume22en_US
dc.identifier.issue11en_US
dc.identifier.doi10.1002/chem.201504870en_US
dcterms.abstractAn efficient reductive Claisen rearrangement, catalyzed by in situ generated copper hydride and stoichiometric in diethoxymethylsilane, has been developed. Yields of up to 95% with good to excellent diastereoselectivities were observed in this reaction. Mechanistic studies showed that the stereospecific rearrangement proceeded via a chair transition state of (E)-silyl ketene acetals as intermediates and not via the copper enolates.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationChemistry - a European journal, 7 Mar. 2016, v. 22, no. 11, p. 3709-3712en_US
dcterms.isPartOfChemistry - a European journalen_US
dcterms.issued2016-03-07-
dc.identifier.scopus2-s2.0-84959421975-
dc.identifier.eissn1521-3765en_US
dc.description.validate202308 bckwen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberABCT-0780-
dc.description.fundingSourceRGCen_US
dc.description.fundingSourceOthersen_US
dc.description.fundingTextThe University of Hong Kong, the State Key Laboratory of Synthetic Chemistryen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS6622167-
dc.description.oaCategoryGreen (AAM)en_US
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