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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.creatorWu, Yen_US
dc.creatorFu, WCen_US
dc.creatorChiang, CWen_US
dc.creatorChoy, PYen_US
dc.creatorKwong, FYen_US
dc.creatorLei, Aen_US
dc.date.accessioned2023-09-18T07:31:27Z-
dc.date.available2023-09-18T07:31:27Z-
dc.identifier.issn1359-7345en_US
dc.identifier.urihttp://hdl.handle.net/10397/101600-
dc.language.isoenen_US
dc.publisherRoyal Society of Chemistryen_US
dc.rightsThis journal is ©The Royal Society of Chemistry 2017en_US
dc.rightsThe following publication Wu, Y., Fu, W. C., Chiang, C. W., Choy, P. Y., Kwong, F. Y., & Lei, A. (2017). Palladium-catalysed mono-α-alkenylation of ketones with alkenyl tosylates. Chemical Communications, 53(5), 952-955 is available at https://doi.org/10.1039/c6cc08392g.en_US
dc.titlePalladium-catalysed mono-α-alkenylation of ketones with alkenyl tosylatesen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage952en_US
dc.identifier.epage955en_US
dc.identifier.volume53en_US
dc.identifier.issue5en_US
dc.identifier.doi10.1039/c6cc08392gen_US
dcterms.abstractThe first example of palladium-catalysed selective mono-α-alkenylation of ketones with alkenyl tosylates is described. In the presence of a Pd/XPhos catalyst system (0.1-1.0 mol%), the reaction provides mono-α-alkenylated ketones in good yields and exhibits excellent substrate tolerance. Highly congested, tri- and tetra-substituted alkenyl tosylates react smoothly and even problematic heteroaryl and aliphatic ketones are applicable substrates. Notably, small β,γ-unsaturated ketones are successfully prepared using acetone as a simple three-carbon feedstock.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationChemical communications, 16 Jan. 2017, v. 53, no. 5, p. 952-955en_US
dcterms.isPartOfChemical communicationsen_US
dcterms.issued2017-01-16-
dc.identifier.scopus2-s2.0-85009231289-
dc.identifier.pmid28044153-
dc.identifier.eissn1364-548Xen_US
dc.description.validate202308 bckwen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberABCT-0715-
dc.description.fundingSourceRGCen_US
dc.description.fundingSourceOthersen_US
dc.description.fundingTextState Key Laboratory of Chirosciences; Joint Supervision Scheme of The Hong Kong Polytechnic Universityen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS54688810-
dc.description.oaCategoryGreen (AAM)en_US
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