Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/101527
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dc.contributorDepartment of Applied Biology and Chemical Technologyen_US
dc.contributorMainland Development Officeen_US
dc.creatorChen, Zen_US
dc.creatorChen, Xen_US
dc.creatorSo, CMen_US
dc.date.accessioned2023-09-18T07:30:43Z-
dc.date.available2023-09-18T07:30:43Z-
dc.identifier.issn0022-3263en_US
dc.identifier.urihttp://hdl.handle.net/10397/101527-
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2019 American Chemical Societyen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.joc.9b00703.en_US
dc.titlePalladium-catalyzed C(sp²)–N bond cross-coupling with triaryl phosphatesen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage6366en_US
dc.identifier.epage6376en_US
dc.identifier.volume84en_US
dc.identifier.issue10en_US
dc.identifier.doi10.1021/acs.joc.9b00703en_US
dcterms.abstractThe first general palladium-catalyzed amination of aryl phosphates is described. The combination of MorDalPhos with [Pd(π-cinnamyl)Cl]₂ enables the amination of electron-rich, electron-neutral, and electron-poor aryl phosphates with a board range of aromatic, aliphatic, and heterocyclic amines. Common functional groups such as ether, keto, ester, and nitrile show an excellent compatibility in this reaction condition. The solvent-free amination reactions are also successful in both solid coupling partners. The gram-scale cross-coupling is achieved by this catalytic system.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationJournal of organic chemistry, 17 May 2019, v. 84, no. 10, p. 6366-6376en_US
dcterms.isPartOfJournal of organic chemistryen_US
dcterms.issued2019-05-17-
dc.identifier.scopus2-s2.0-85065787153-
dc.identifier.pmid31038958-
dc.identifier.eissn1520-6904en_US
dc.description.validate202308 bckwen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberABCT-0394-
dc.description.fundingSourceOthersen_US
dc.description.fundingTextThe Hong Kong Polytechnic University Start-up Fund; Shenzhen Strategic New Industry Development Research Fund of Shenzhen Science, Technology and Innovation Commissionen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS13911091-
dc.description.oaCategoryGreen (AAM)en_US
Appears in Collections:Journal/Magazine Article
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