Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/100423
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dc.contributorDepartment of Applied Physicsen_US
dc.creatorZhou, Wen_US
dc.creatorXue, Len_US
dc.creatorLü, Xen_US
dc.creatorGao, Hen_US
dc.creatorLi, Yen_US
dc.creatorXin, Sen_US
dc.creatorFu, Gen_US
dc.creatorCui, Zen_US
dc.creatorZhu, Yen_US
dc.creatorGoodenough, JBen_US
dc.date.accessioned2023-08-08T01:56:03Z-
dc.date.available2023-08-08T01:56:03Z-
dc.identifier.issn1530-6984en_US
dc.identifier.urihttp://hdl.handle.net/10397/100423-
dc.language.isoenen_US
dc.publisherAmerican Chemical Societyen_US
dc.rights© 2016 American Chemical Societyen_US
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://doi.org/10.1021/acs.nanolett.6b04044.en_US
dc.subjectFramework oxideen_US
dc.subjectManganese oxidationen_US
dc.subjectNa+ transporten_US
dc.subjectSodium cathodesen_US
dc.subjectSTEMen_US
dc.titleNaxMV(PO₄)₃ (M = Mn, Fe, Ni) structure and properties for sodium extractionen_US
dc.typeJournal/Magazine Articleen_US
dc.identifier.spage7836en_US
dc.identifier.epage7841en_US
dc.identifier.volume16en_US
dc.identifier.issue12en_US
dc.identifier.doi10.1021/acs.nanolett.6b04044en_US
dcterms.abstractNASICON (Na+ super ionic conductor) structures of NaxMV(PO₄)₃ (M = Mn, Fe, Ni) were prepared, characterized by aberration-corrected STEM and synchrotron radiation, and demonstrated to be durable cathode materials for rechargeable sodium-ion batteries. In Na₄MnV(PO₄)₃, two redox couples of Mn³⁺/Mn²⁺ and V⁴⁺/V³⁺ are accessed with two voltage plateaus located at 3.6 and 3.3 V and a capacity of 101 mAh g⁻¹ at 1 C. Furthermore, the Na4MnV(PO4)3 cathode delivers a high initial efficiency of 97%, long durability over 1000 cycles, and good rate performance to 10 C. The robust framework structure and stable electrochemical performance makes it a reliable cathode materials for sodium-ion batteries.en_US
dcterms.accessRightsopen accessen_US
dcterms.bibliographicCitationNano letters, 14 Dec. 2016, v. 16, no. 12, p. 7836-7841en_US
dcterms.isPartOfNano lettersen_US
dcterms.issued2016-12-14-
dc.identifier.scopus2-s2.0-85006246894-
dc.identifier.eissn1530-6992en_US
dc.description.validate202308 bcvcen_US
dc.description.oaAccepted Manuscripten_US
dc.identifier.FolderNumberAP-0731-
dc.description.fundingSourceOthersen_US
dc.description.fundingTextThe National Science Foundation; The Hong Kong Polytechnic University; Robert A. Welch Foundationen_US
dc.description.pubStatusPublisheden_US
dc.identifier.OPUS6705092-
dc.description.oaCategoryGreen (AAM)en_US
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