Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/61243
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Title: Open-air oxidative mizoroki-heck reaction of arylsulfonyl hydrazides with alkenes
Authors: Yuen, OY
So, CM
Kwong, FY 
Issue Date: 2016
Source: RSC advances, 2016, v. 6, no. 33, p. 27584-27589
Abstract: A palladium(ii)-catalyzed oxidative Mizoroki-Heck reaction of arylsulfonyl hydrazides with alkenes was developed employing atmospheric air as the sole oxidant in an open-vessel manner. By using palladium(ii) acetate associating with inexpensive, air-stable and moisture stable pyridine ligand L9 as the catalyst system, the efficiency of the reaction could be significantly enhanced. A wide range of arylsulfonyl hydrazides underwent the oxidative Mizoroki-Heck reaction with alkenes smoothly. Good-to-excellent product yields and excellent regio- and stereoselectivity were achieved. Functional groups such as halo, ester etc. were well-tolerated under these optimized reaction conditions.
Publisher: Royal Society of Chemistry
Journal: RSC advances 
EISSN: 2046-2069
DOI: 10.1039/c6ra03188a
Rights: The article is licensed under a Creative Commons Attribution 3.0 Unported (CC BY 3.0) <https://creativecommons.org/licenses/by-nc/3.0/>
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