Chiral trivalent gold complex as well as preparation method and application thereof

Abstract

The invention provides a chiral trivalent gold complex. The chiral trivalent gold complex consists of two carbon-gold covalent bonds, an oxygen-gold covalent bond and a nitrogen-gold coordination bond, has a chiral binaphthol and oxazoline ligand framework or a chiral binaphthol and ortho-substituted pyridine ligand framework and has a compound shown in a general formula I or general formula II and a racemate and optical isomer shown in a general formula I or a general formula II. 本发明提供了一种手性三价金络合物，所述手性三价金络合物由两个碳‑金共价键、一个氧‑金共价键以及一个氮‑金配位键构成，具有手性联萘酚和噁唑啉配体骨架，或具有手性联萘酚和邻位取代吡啶配体骨架，所述手性三价金络合物具有下述通式I或通式II的化合物，以及所述通式I或通式II的消旋体和旋光异构体，