Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/94137
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | en_US |
dc.creator | Lam, LY | en_US |
dc.creator | Chan, KH | en_US |
dc.creator | Ma, C | en_US |
dc.date.accessioned | 2022-08-11T01:07:21Z | - |
dc.date.available | 2022-08-11T01:07:21Z | - |
dc.identifier.issn | 0022-3263 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/94137 | - |
dc.language.iso | en | en_US |
dc.publisher | American Chemical Society | en_US |
dc.rights | © 2022 American Chemical Society | en_US |
dc.rights | This document is the Accepted Manuscript version of a Published Work that appeared in final form in The Journal of Organic Chemistry, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acs.joc.2c00777. | en_US |
dc.title | Copper-catalyzed synthesis of functionalized aryl sulfonamides from sodium sulfinates in green solvents | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 8802 | en_US |
dc.identifier.epage | 8810 | en_US |
dc.identifier.volume | 87 | en_US |
dc.identifier.issue | 13 | en_US |
dc.identifier.doi | 10.1021/acs.joc.2c00777 | en_US |
dcterms.abstract | Functionalized aryl sulfonamides are important building blocks in the pharmaceutical industry. A one-step synthesis catalyzed by a copper salt was developed using stable solid commodity chemicals in sulfolane or, alternatively, in green solvents such as γ-valerolactone, iPrOAc, or nBuOAc with acetic acid. The method tolerated diverse functional groups commonly presented in current medicines and drug intermediates. The mechanistic study showed a radical coupling pathway between the sulfonyl and anilinium radicals through the use of K2S2O8 and copper catalyst, respectively. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Journal of organic chemistry, 2022, v. 87, no. 13, p. 8802-8810 | en_US |
dcterms.isPartOf | Journal of organic chemistry | en_US |
dcterms.issued | 2022 | - |
dc.identifier.scopus | 2-s2.0-85134080256 | - |
dc.identifier.eissn | 1520-6904 | en_US |
dc.description.validate | 202208 bcrc | en_US |
dc.description.oa | Accepted Manuscript | en_US |
dc.identifier.FolderNumber | a1609 | - |
dc.identifier.SubFormID | 45608 | - |
dc.description.fundingSource | RGC | en_US |
dc.description.fundingSource | Others | en_US |
dc.description.fundingText | Others: Hong Kong Polytechnic University | en_US |
dc.description.pubStatus | Published | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Long_Copper-Catalyzed_Synthesis_Functionalized.pdf | Pre-Published version | 1.18 MB | Adobe PDF | View/Open |
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