Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/94011
Title: | Chan-Lam-Type C-S coupling reaction by sodium aryl sulfinates and organoboron compounds | Authors: | Lam, LY Ma, C |
Issue Date: | 2021 | Source: | Organic letters, 2021, v. 23, no. 15, p. 6164-6168 | Abstract: | A Chan-Lam-Type C-S coupling reaction using sodium aryl sulfinates has been developed to provide diaryl thioethers in up to 92% yields in the presence of a copper catalyst and potassium sulfite. Both electron-rich and electron-poor sodium aryl sulfinates and diverse organoboron compounds were tolerated for the synthesis of aryl and heteroaryl thioethers and dithioethers. The mechanistic study suggested that potassium sulfite was involved in the deoxygenation of sulfinate through a radical process. | Publisher: | American Chemical Society | Journal: | Organic letters | ISSN: | 1523-7060 | EISSN: | 1523-7052 | DOI: | 10.1021/acs.orglett.1c02299 | Rights: | © 2021 American Chemical Society This document is the Accepted Manuscript version of a Published Work that appeared in final form in https://pubs.acs.org/journal/aamick, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://dx.doi.org/10.1021/acs.orglett.1c02299. ACS Applied Materials & Interfaces is available at https://pubs.acs.org/journal/aamick. |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Lam_Chan-Lam-Type_C-S_Sodium.pdf | Pre-Published version | 1.21 MB | Adobe PDF | View/Open |
Page views
53
Last Week
1
1
Last month
Citations as of May 5, 2024
Downloads
96
Citations as of May 5, 2024
SCOPUSTM
Citations
13
Citations as of May 3, 2024
WEB OF SCIENCETM
Citations
13
Citations as of May 2, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.