Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/92627
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Industrial and Systems Engineering | en_US |
dc.creator | Zhang, X | en_US |
dc.creator | Chen, Y | en_US |
dc.creator | Srinivas, K | en_US |
dc.creator | Yu, B | en_US |
dc.creator | Ma, F | en_US |
dc.creator | Wang, B | en_US |
dc.creator | Wang, X | en_US |
dc.creator | He, J | en_US |
dc.creator | Xu, ZL | en_US |
dc.date.accessioned | 2022-05-04T03:20:40Z | - |
dc.date.available | 2022-05-04T03:20:40Z | - |
dc.identifier.issn | 0021-9797 | en_US |
dc.identifier.uri | http://hdl.handle.net/10397/92627 | - |
dc.language.iso | en | en_US |
dc.publisher | Academic Press | en_US |
dc.rights | © 2021 Elsevier Inc. All rights reserved. | en_US |
dc.rights | © 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/. | en_US |
dc.rights | The following publication Zhang, X., Chen, Y., Srinivas, K., Yu, B., Ma, F., Wang, B., Wang, X., He, J., & Xu, Z.-L. (2022). Lithiophilic Mo3N2/MoN as multifunctional interlayer for dendrite-free and ultra-stable lithium metal batteries. Journal of Colloid and Interface Science, 612, 332-341 is available at https://dx.doi.org/10.1016/j.jcis.2021.12.143. | en_US |
dc.subject | DFT calculations | en_US |
dc.subject | In-situ reaction | en_US |
dc.subject | Li3N-rich layer | en_US |
dc.subject | Lithium metal batteries | en_US |
dc.subject | Mo3N2/MoN heterostructure | en_US |
dc.title | Lithiophilic Mo₃N₂/MoN as multifunctional interlayer for dendrite-free and ultra-stable lithium metal batteries | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 332 | en_US |
dc.identifier.epage | 341 | en_US |
dc.identifier.volume | 612 | en_US |
dc.identifier.doi | 10.1016/j.jcis.2021.12.143 | en_US |
dcterms.abstract | The formation of lithium dendrite and the unstable electrode/electrolyte interface, especially at high rates, are the dominant obstacles impeding the implementation of lithium metal batteries (LMBs). To tackle these fundamental challenges, here we propose a lithiophilic Mo₃N₂/MoN heterostructure (designated as MoNx) interlayer for dendrite-free and ultra-stable lithium metal anodes for the first time. The MoNx interlayer presents excellent electrolyte wettability, fast lithium diffusion kinetics and strong mechanical strength, which function synergistically to inhibit lithium dendrite growth. During cycling, an in-situ formation of Li3N-rich solid electrolyte interphase layer and metallic Mo phase can regulate the Li-ion conductivity and Li metal deposition, thus indicating uniform and compact Li plating. Above ameliorating features accompany an ultra-long-life of 2000 h at a high current density of 5 mA cm−2 for the MoNx-Li anode. The feasibility of the MoNx-Li anode in LMB is further confirmed in conjunction with LiFePO4 cathodes. The full cells deliver exceptionally high-capacity retentions of above 82.0% after 500 cycles at 1C and 425 cycles at 3C, which are among the best thus far reported for LMBs. This work provides both new insights towards functional interlayer design and effective transition-metal nitrides for practical LMBs. | en_US |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | Journal of colloid and interface science, 15 Apr. 2022, v. 612, p. 332-341 | en_US |
dcterms.isPartOf | Journal of colloid and interface science | en_US |
dcterms.issued | 2022-04-15 | - |
dc.identifier.scopus | 2-s2.0-85122261497 | - |
dc.identifier.pmid | 34998193 | - |
dc.identifier.eissn | 1095-7103 | en_US |
dc.description.validate | 202205 bcvc | en_US |
dc.description.oa | Accepted Manuscript | en_US |
dc.identifier.FolderNumber | a1300, ISE-0002 | - |
dc.identifier.SubFormID | 44515 | - |
dc.description.fundingSource | Others | en_US |
dc.description.fundingText | National Natural Science Foundation of China; Sichuan Science and Technology program; Reformation and Development Funds for Local Region Universities from China Government in 2020; China Postdoctoral Science Foundation; Academic support program for doctoral students of University of Electronic Science and Technology of China; The Hong Kong Polytechnic University | en_US |
dc.description.pubStatus | Published | en_US |
dc.identifier.OPUS | 60650163 | - |
dc.description.oaCategory | Green (AAM) | en_US |
Appears in Collections: | Journal/Magazine Article |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
Zhang_Lithiophilic_multifunctional_Interlayer.pdf | Pre-Published version | 2.18 MB | Adobe PDF | View/Open |
Page views
60
Last Week
0
0
Last month
Citations as of May 19, 2024
Downloads
2
Citations as of May 19, 2024
SCOPUSTM
Citations
6
Citations as of May 16, 2024
WEB OF SCIENCETM
Citations
5
Citations as of May 16, 2024
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.