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http://hdl.handle.net/10397/89490
Title: | Facile one-step preparation of 3D nanoporous Cu/Cu6Sn5 microparticles as anode material for lithium-ion batteries with superior lithium storage properties | Authors: | Xiang, P Liu, W Chen, X Zhang, S Shi, S |
Issue Date: | Nov-2020 | Source: | Metallurgical and materials transactions. A, Physical metallurgy and materials science, Nov. 2020, v. 51, no. 11, p. 5965-5973 | Abstract: | In this article, three-dimensional nanoporous Cu/Cu6Sn5 microparticles (3D-NP Cu/Cu6Sn5 MPs) were prepared by one-step chemical dealloying of Cu20Sn80 (at%) alloy slices in a mixed aqueous solution of HF and HNO3 and then filled into a three-dimensional porous copper foam (3D-PCF) skeleton as anode (3D-PCF@Cu/Cu6Sn5) for lithium-ion batteries (LIBs). The results show that the ellipsoidal 3D-NP Cu/Cu6Sn5 MPs with feature sizes of 3 to 8 μm are composed of numerous uniform nanoparticles (100 to 200 nm) and plenty of voids. Compared with similar Sn-based electrodes in this work and other published reports, the as-prepared electrode delivers more outstanding electrochemical performance with a superior reversible capacity of 1.90 mAh cm−2, 84.44% capacity retention and > 99.5% coulombic efficiency upon 200 cycles. The cycling stability and integrity of the overall structure of the composite electrode have been greatly enhanced under the synergistic effect of the buffer effect of copper as the inactive component, the unique hierarchical porous electrode architecture and the effective limitation in three dimensions of the 3D-PCF skeleton. We are confident that this work can provide new-generation LIBs with a promising anode candidate and a facile method of dealloying, and a subsequent filling step can achieve the practical production and application of high-performance LIBs. | Publisher: | Springer | Journal: | Metallurgical and materials transactions. A, Physical metallurgy and materials science | ISSN: | 1073-5623 | EISSN: | 1543-1940 | DOI: | 10.1007/s11661-020-05980-1 | Rights: | © The Minerals, Metals & Materials Society and ASM International 2020 This is a post-peer-review, pre-copyedit version of an article published in Metallurgical and Materials Transactions A. The final authenticated version is available online at: https://doi.org/10.1007/s11661-020-05980-1. Xiang, P., Liu, W., Chen, X. et al. Facile One-Step Preparation of 3D Nanoporous Cu/Cu6Sn5 Microparticles as Anode Material for Lithium-Ion Batteries with Superior Lithium Storage Properties. Metall Mater Trans A 51, 5965–5973 (2020). Published: 08 September 2020. Issue Date: November 2020. |
Appears in Collections: | Journal/Magazine Article |
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B2_MMTA-2020-P._Xiang.pdf | Pre-Published version | 2.1 MB | Adobe PDF | View/Open |
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