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http://hdl.handle.net/10397/88754
Title: | A single component white electroluminescent device fabricated from a metallo-organic terbium complex | Authors: | Ilmi, R Khan, MS Sun, WD Zhou, L Wong, WY Raithby, PR |
Issue Date: | 28-Nov-2019 | Source: | Journal of materials chemistry C, 28 Nov. 2019, v. 7, no. 44, p. 13966-13975 | Abstract: | Two new mixed ligand complexes [Eu(tfac)(3)(DPEPO)] (Eu-1) and [Tb(tfac)(3)(DPEPO)] (Tb-2) incorporating trifluoroacetylacetone (Htfac) and bis(2-(diphenylphosphino)phenyl)ether oxide (DPEPO) were synthesized in gram-scale quantities and used as emitters to fabricate single- and double-EML (light-emitting layer) electroluminescence (EL) devices. The single-EML device with the structure: ITO/HAT-CN (6 nm)/HAT-CN (0.2 wt%):TAPC (50 nm)/Eu-1 (1-6 wt%): 26DCzPPy (10 nm)/Tm3PyP26PyB (50 nm)/LiF (1 nm)/Al (100 nm) showed light red (CIE, x: 0.574; y: 0.275) emission for the Eu-1 based EL devices due to the presence of a host emission with a brightness of 1274 cd m(-2), current efficiency (eta(c)), power efficiency (eta(p)) and external quantum efficiency (EQE) of 0.58 cd A(-1), 0.68 lm W-1, and 0.70%, respectively. The single-EML device for the Tb-2 complex with the same device structure displayed white-light emission. The optimized single-EML device of Tb-2 with 14.0 wt% doping concentration showed an impressive EL performance with brightness of 1637 cd m(-2), eta(c) approximate to 3.05 cd A(-1), eta(p) approximate to 2.80 lm W-1, EQE approximate to 1.4%, Vturn-on approximate to 3.1 V, respectively. This is the first report of single component white organic light emitting diode (W-OLED) fabricated from an organo-Tb(iii) complex. The W-OLEDs show low turn-on voltages (Vturn-on) approximate to 3.1 V and are thus advantageous in lowering the power consumption of the OLED display. | Publisher: | Royal Society of Chemistry | Journal: | Journal of materials chemistry C | ISSN: | 2050-7526 | EISSN: | 2050-7534 | DOI: | 10.1039/c9tc04653d | Rights: | This article is licensed under a Creative Commons Attibution 3.0 Unported Licence (https://creativecommons.org/licenses/by/3.0/) This journal is © The Royal Society of Chemistry 2019 The following publication Ilmi, R., Khan, M. S., Sun, W. D., Zhou, L., Wong, W. Y., & Raithby, P. R. (2019). A single component white electroluminescent device fabricated from a metallo-organic terbium complex. Journal of Materials Chemistry C, 7(44), 13966-13975 is available at https://dx.doi.org/10.1039/c9tc04653d |
Appears in Collections: | Journal/Magazine Article |
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