Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/81145
Title: Boosting the adhesivity of -conjugated polymers by embedding platinum acetylides towards high-performance thermoelectric composites
Authors: Wan, T
Yin, XJ
Pan, CJ
Liu, DQ
Zhou, XY
Gao, CM
Wong, WY 
Wang, L
Keywords: Thermoelectric
Platinum acetylides
Composite films
Adhesivity
Carbon nanotubes
Issue Date: 2019
Publisher: Molecular Diversity Preservation International
Source: Polymers, Apr. 2019, v. 11, no. 4, 593, p. 1-14 How to cite?
Journal: Polymers 
Abstract: Single-walled carbon nanotubes (SWCNTs) incorporated with -conjugated polymers, have proven to be an effective approach in the production of advanced thermoelectric composites. However, the studied polymers are mainly limited to scanty conventional conductive polymers, and their performances still remain to be improved. Herein, a new planar moiety of platinum acetylide in the -conjugated system is introduced to enhance the intermolecular interaction with the SWCNTs via - and d- interactions, which is crucial in regulating the thermoelectric performances of SWCNT-based composites. As expected, SWCNT composites based on the platinum acetylides embedded polymers displayed a higher power factor (130.7 +/- 3.8 Wm(-1)K(-2)) at ambient temperature than those without platinum acetylides (59.5 +/- 0.7 Wm(-1)K(-2)) under the same conditions. Moreover, the strong interactions between the platinum acetylide-based polymers and the SWCNTs are confirmed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) measurements.
URI: http://hdl.handle.net/10397/81145
ISSN: 2073-4360
DOI: 10.3390/polym11040593
Rights: © 2019 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/).
The following publication Wan, T.; Yin, X.; Pan, C.; Liu, D.; Zhou, X.; Gao, C.; Wong, W.-Y.; Wang, L. Boosting the Adhesivity of π-Conjugated Polymers by Embedding Platinum Acetylides towards High-Performance Thermoelectric Composites. Polymers 2019, 11, 593, 14 pages is available at https://dx.doi.org/10.3390/polym11040593
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