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Title: Influence of side-chain regiochemistry on the transistor performance of high-mobility, all-donor polymers
Authors: Fei, Z
Pattanasattayavong, P
Han, Y
Schroeder, BC
Yan, F 
Kline, RJ
Anthopoulos, TD
Heeney, M
Issue Date: 2014
Publisher: American Chemical Society
Source: Journal of the American Chemical Society, 2014, v. 136, no. 43, p. 15154-15157 How to cite?
Journal: Journal of the American Chemical Society 
Abstract: Three novel polythiophene isomers are reported whereby the only difference in structure relates to the regiochemistry of the solubilizing side chains on the backbone. This is demonstrated to have a significant impact on the optoelectronic properties of the polymers and their propensity to aggregate in solution. These differences are rationalized on the basis of differences in backbone torsion. The polymer with the largest effective conjugation length is demonstrated to exhibit the highest field-effect mobility, with peak values up to 4.6 cm2 V-1 s-1.
ISSN: 0002-7863
EISSN: 1520-5126
DOI: 10.1021/ja508798s
Rights: © 2014 American Chemical Society
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The following publication Fei, Z., Pattanasattayavong, P., Han, Y., Schroeder, B. C., Yan, F., Kline, R. J., . . . Heeney, M. (2014). Influence of side-chain regiochemistry on the transistor performance of high-mobility, all-donor polymers. Journal of the American Chemical Society, 136(43), 15154-15157 is available at
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