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Title: | Is steam addition necessary for the landfill gas fueled solid oxide fuel cells? | Authors: | Ni, M | Issue Date: | 13-Dec-2013 | Source: | International journal of hydrogen energy, 13 Dec. 2013, v. 38, no. 36, p. 16373-16386 | Abstract: | Landfill gas in Hong Kong – a mixture of about 50% (by volume) CH₄ and 50% CO₂ – can be utilized for power generation in a solid oxide fuel cell (SOFC). Conventional way of utilizing CH₄ in a SOFC is by adding H₂O to CH₄ to initiate methane steam reforming (MSR) and water gas shift reaction (WGSR). As the methane carbon dioxide reforming (MCDR: CH₄ + CO₂ ↔ 2CO + 2 H₂) is feasible in the SOFC anode, it is unknown whether H2O is needed or not for landfill gas fueled SOFC. In this study, a numerical model is developed to investigate the characteristics of SOFC running on landfill gas. Parametric simulations show that H₂O addition may decrease the performance of short SOFC at typical operating conditions as H₂O dilute the fuel concentration. However, it is interesting to find that H₂O addition is needed at reduced operating temperature, lower operating potential, or in SOFC with longer gas channel, mainly due to less temperature reduction in the downstream and easier oxidation of H₂ than CO. This preliminary study could help identify strategies for converting landfill gas into electrical power in Hong Kong. | Keywords: | Landfill gas Solid oxide fuel cell Methane carbon dioxide reforming Modeling |
Publisher: | Pergamon Press | Journal: | International journal of hydrogen energy | ISSN: | 0360-3199 | EISSN: | 1879-3487 | DOI: | 10.1016/j.ijhydene.2013.10.006 | Rights: | Copyright © 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved. Posted with permission of International Association of Hydrogen Energy. |
Appears in Collections: | Journal/Magazine Article |
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Ni_is_steam_addition.pdf | 6.37 MB | Adobe PDF | View/Open |
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