Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/5046
Title: A study of the vibronic structure in the Hel excited photoelectron spectrum of CO₂involving the X ²Π[sub g] and A ² Π[sub u] ionic states
Authors: Baltzer, P
Chau, FT
Eland, JHD
Karlsson, L
Lundqvist, M
Rostas, J
Tam, KY
Veenhuizen, H
Wannberg, B
Keywords: Carbon dioxide
Photoelectron spectroscopy
Excited states
Vibronic states
Resolution
Complexes
Fine structure
Coupling
Issue Date: 8-Jun-1996
Publisher: American Institute of Physics
Source: Journal of chemical physics, 8 June 1996, v. 104, no. 22, p. 8922-8931 How to cite?
Journal: Journal of chemical physics 
Abstract: The HeI excited photoelectron spectrum of the CO₂molecule covering the X ²Π[sub g] and A ²Π[sub u] ionic states has been recorded at a resolution of better than 5 meV. Complex vibrational structures are resolved in both photoelectron bands. In the X ²Π[sub g] state, the v₂and v₃modes are observed to be excited in both an odd and even numbers of quanta in addition to the v₁mode, whereas for the A ²Π[sub u] state the spectrum is dominated by excitations of the v₁mode alone and in combinations with excitations of the v₂mode in two quanta involving strong Fermi resonance. The observed spectrum has been assigned by comparison with optical spectra and with calculations of the vibrational fine structure including vibronic and spin–orbit coupling.
URI: http://hdl.handle.net/10397/5046
ISSN: 0021-9606 (print)
1089-7690 (online)
DOI: 10.1063/1.471626
Rights: © 1996 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in F. T. Chau et al., J. Chem. Phys. 104, 8922 (1996) and may be found at http://link.aip.org/link/?jcp/104/8922.
Appears in Collections:Journal/Magazine Article

Files in This Item:
File Description SizeFormat 
Baltzer_Study_vibronic_structure.pdf800.34 kBAdobe PDFView/Open
Access
View full-text via PolyU eLinks SFX Query
Show full item record

SCOPUSTM   
Citations

32
Last Week
0
Last month
Citations as of Feb 5, 2016

WEB OF SCIENCETM
Citations

32
Citations as of Feb 5, 2016

Page view(s)

190
Checked on Feb 7, 2016

Google ScholarTM
Citations

loading...

Altmetric



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.