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Title: Recent advances in the development of chiral gold complexes for catalytic asymmetric catalysis
Authors: Jiang, JJ 
Wong, MK 
Issue Date: 1-Mar-2021
Source: Chemistry, an Asian journal, 1 Mar. 2021, v. 16, no. 5, p. 364-377
Abstract: Asymmetric gold catalysis has been rapidly developed in the past ten years. Breakthroughs have been made by rational design and meticulous selection of chiral ligands. This review summarizes newly developed gold-catalyzed enantioselective organic transformations and recent progress in ligand design (since 2016), organized according to different types of chiral ligands, including bisphosphine ligands, monophosphine ligands, phosphite-derived ligands, and N-heterocyclic carbene ligands for asymmetric gold(I) catalysis as well as heterocyclic carbene ligands and oxazoline ligands for asymmetric gold(III) catalysis.
Keywords: Asymmetric catalysis
Enantioselectivity
Gold
Homogeneous catalysis
Ligand design
Publisher: Wiley-VCH
Journal: Chemistry, an Asian journal 
ISSN: 1861-4728
EISSN: 1861-471X
DOI: 10.1002/asia.202001375
Rights: © 2021 Wiley-VCH GmbH
This is the peer reviewed version of the following article: Jiang, J. J., & Wong, M. K. (2021). Recent advances in the development of chiral gold complexes for catalytic asymmetric catalysis. Chemistry–An Asian Journal, 16(5), 364-377, which has been published in final form at https://doi.org/10.1002/asia.202001375. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited.
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