Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/9867
Title: Enantioselective addition of diethylzinc to aldehydes catalyzed by optically active C-2-symmetrical bis-beta-amino alcohols
Authors: Xu, QY
Zhu, GM
Pan, XF
Chan, ASC
Keywords: Asymmetric reactions
Diethylzinc
C-2-symmetrical bis-beta-amino alcohols
Aldehyde
Issue Date: 2002
Publisher: Wiley-Liss
Source: Chirality, 2002, v. 14, no. 9, p. 716-723 How to cite?
Journal: Chirality 
Abstract: The syntheses of new optically active C-2-symmetrical bis-beta-amino alcohols 1-6 from (S)-2-(1-hydroxy-1,1-diphenylmethyl)-pyrrolidine are described. Especially attention is focused on bridges, which link the two beta-amino alcohol units. These new chiral ligands have been successfully applied in the catalytic enantioselective addition of diethylzinc to aldehydes to give sec-alcohols in good yields with up to 95% enantiomeric excess.
URI: http://hdl.handle.net/10397/9867
ISSN: 0899-0042
DOI: 10.1002/chir.10132
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