Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/9855
Title: Dependence of sulfadiazine oxidative degradation on physicochemical properties of manganese dioxides
Authors: Liu, C
Zhang, L
Li, F
Wang, Y
Gao, Y
Li, X
Cao, W
Feng, C
Dong, J
Sun, L
Issue Date: 2009
Publisher: American Chemical Society
Source: Industrial and engineering chemistry research, 2009, v. 48, no. 23, p. 10408-10413 How to cite?
Journal: Industrial and engineering chemistry research 
Abstract: Manganese dioxides as active oxidants are the common minerals in environment, and different types of manganese dioxides may exhibit varied oxidative activity. In this study, eight manganese dioxides were used to conduct sulfadiazine (SD) oxidative degradation. SD can be oxidatively degraded and even mineralized by these manganese dioxides, and the toxicity of the SD sample can also be reduced significantly. The experiments in this study demonstrated that the kinetic reaction rate constant k values of SD degradation strongly depended on the physicochemical properties of different manganese dioxides, including average oxidation state (AOS), reductive potential (Eh), pH at the point of zero charge (pHPZC), and apparent activation energy (Ea). The k values were positively correlated with the AOS and Eh, while negatively correlated with pHPZC and Ea. The values of these physicochemical properties can be used to quantitatively estimate the oxidative activity of a manganese dioxide to some extent for better understanding of the degradation of organic pollutants with manganese dioxides.
URI: http://hdl.handle.net/10397/9855
ISSN: 0888-5885
EISSN: 1520-5045
DOI: 10.1021/ie900812j
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