Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/8069
Title: Asymmetric organocatalytic allylic substitution of Morita-Baylis-Hillman carbonates with allylamines for the synthesis of 2,5-dihydropyrroles
Authors: Sun, W
Ma, X
Hong, L
Wang, R
Issue Date: 2011
Publisher: American Chemical Society
Source: Journal of organic chemistry, 2011, v. 76, no. 19, p. 7826-7833 How to cite?
Journal: Journal of organic chemistry 
Abstract: (Figure presented) The asymmetric allylic substitution reaction of MBH carbonates with allylamines has been developed, which affords N-allyl-β-amino-α-methylene esters in high yields and enantioselectivities. After a subsequent ring-closure metathesis of the products, a series of optically active 2,5-dihydropyrroles could be obtained smoothly in high yields without any loss of enantioselectivity. Finally, a tentative mechanism for rationalization of the reaction has been proposed.
URI: http://hdl.handle.net/10397/8069
ISSN: 0022-3263
EISSN: 1520-6904
DOI: 10.1021/jo2011522
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