Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/78900
Title: Electrochemical oxidative radical oxysulfuration of styrene derivatives with thiols and nucleophilic oxygen sources
Authors: Wang, Y
Deng, LL
Mei, HB
Du, BN 
Han, JL
Pan, Y
Issue Date: 2018
Publisher: Royal Society of Chemistry
Source: Green chemistry, 7 Aug. 2018, v. 20, no. 15, p. 3444-3449 How to cite?
Journal: Green chemistry 
Abstract: Oxydifunctionalization of olefins represents a powerful tool and yet poses a challenging task. Previous methods have usually required a stoichiometric amount of a strong oxidant and an expensive transition-metal catalyst. This work describes the first example of the electrochemical oxysulfuration reaction of olefins with thiols and nucleophilic oxygen sources. This electrochemical difunctionalization reaction is conducted under catalyst- and oxidant-free conditions, and shows good substrate generality, affording thio-substituted alcohols, ethers and gamma-lactones in good chemical yields and with excellent regioselectivities. This work represents a new and green strategy for the difunctionalization of olefins, and also provides a complementary and highly valuable prospect for current methodologies for the synthesis of thio-substituted compounds.
URI: http://hdl.handle.net/10397/78900
ISSN: 1463-9262
DOI: 10.1039/c8gc01337c
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