Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/76298
Title: Regioselective synthesis of polycyclic and heptagon-embedded aromatic compounds through a versatile pi-extension of Aryl halides
Authors: Fu, WC 
Wang, Z
Chan, WTK 
Lin, Z
Kwong, FY 
Keywords: C-H functionalization
Cross-coupling
Decarboxylation
Palladium
Polycyclic aromatic hydrocarbons
Issue Date: 2017
Publisher: Wiley-VCH
Source: Angewandte chemie international edition, 2017, v. 56, no. 25, p. 7166-7170 How to cite?
Journal: Angewandte chemie international edition 
Abstract: A versatile pi-extension reaction was developed based on the three-component cross-coupling of aryl halides, 2-haloarylcarboxylic acids, and norbornadiene. The transformation is driven by the direction and subsequent decarboxylation of the carboxyl group, while norbornadiene serves as an ortho-C-H activator and ethylene synthon via a retro-Diels-Alder reaction. Comprehensive DFT calculations were performed to account for the catalytic intermediates.
URI: http://hdl.handle.net/10397/76298
ISSN: 1433-7851
EISSN: 1521-3773
DOI: 10.1002/anie.201703551
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