Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/76275
Title: Mobility and phytoavailability of As and Pb in a contaminated soil using pine sawdust biochar under systematic change of redox conditions
Authors: Beiyuan, J 
Awad, YM
Beckers, F
Tsang, DCW 
Ok, YS
Rinklebe, J
Keywords: Trace elements
Soil remediation
Redox processes
Charcoal
Immobilization
Issue Date: 2017
Publisher: Pergamon Press
Source: Chemosphere, 2017, v. 178, p. 110-118 How to cite?
Journal: Chemosphere 
Abstract: Biochar has been adopted to control the mobility and phytoavailability of trace elements (TEs) in soils. To date, no attempt has been made to determine the mobility and phytoavailability of arsenic (As) and lead (Pb) in a contaminated soil with biochars as amendments under predefined redox potentials (E-H). Thus, in this study, a soil contaminated with As and Pb (2047 and 1677 mg kg(-1), respectively) was pre-incubated for 105 days with three amendments (pine sawdust biomass (BM) and two biochars produced from the same feedstock at 300 degrees C (BC300) and 550 degrees C (BC550)). The aged samples were then exposed to dynamic E-H conditions to evaluate the mobility and phytoavailability of As and Pb after immobilization. The BM amendment significantly decreased and the BC300 slightly reduced the mobility and phytoavailability of As and Pb, which may be related to the oxygen-containing functional groups on the surface of BM and BC300. In contrast, BC550 increased the mobility of As at -300 to -100 mV and 100 mV, enhanced the phytoavailability of As under oxidizing condition (>100 mV), but reduced the phytoavailability of Pb, which might be caused by the properties of amendments and redox chemistry of the TEs. The effectiveness of BM and biochars for the stabilization of As and Pb varied under dynamic EH conditions, which indicates that detailed investigations should be conducted before the applications of biochar as soil amendment under variable environmental conditions, especially for contaminated paddy soils.
URI: http://hdl.handle.net/10397/76275
ISSN: 0045-6535
EISSN: 1879-1298
DOI: 10.1016/j.chemosphere.2017.03.022
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