Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/76034
Title: Cascade amination and acetone monoarylation with aryl iodides by Palladium/Norbornene cooperative catalysis
Authors: Fu, WC 
Zheng, B 
Zhao, QY 
Chan, WTK 
Kwong, FY 
Issue Date: 2017
Publisher: American Chemical Society
Source: Organic letters, 2017, v. 19, no. 16, p. 4335-4338 How to cite?
Journal: Organic letters 
Abstract: A palladium/norbornene cocatalyzd three-component reaction of aryl iodides, O-benzoylhydroxylamines, and acetone is reported. o'-Aminoaryl acetones or O,O'-diaminoaryl acetones are efficiently prepared via tandem ortho-C-H amination/ipso-C-I alpha-arylation sequence,and the regiospecificity has been confirmed by X-ray analysis, The proposed method addresses the condensation/amination of free-N-H-bearing substrates acetone monoarylations and the synthesis of extremely congested 2,6-disubstituted aryl acetones:
URI: http://hdl.handle.net/10397/76034
ISSN: 1523-7060
EISSN: 1523-7052
DOI: 10.1021/acs.orglett.7b02023
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