Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/75763
Title: Flower-like MoSe2/C composite with expanded (002) planes of few-layer MoSe2 as the anode for high-performance sodium-ion batteries
Authors: Li, J
Hu, HX
Qin, FR 
Zhang, P
Zou, L
Wang, HB
Zhang, K
Lai, YQ
Keywords: Anode
Expanded layer space
Flower-like
MoSe2
Sodium-ion batteries
Issue Date: 2017
Publisher: Wiley-VCH
Source: Chemistry - a European journal, 2017, v. 23, no. 56, p. 14004-14010 How to cite?
Journal: Chemistry - a European journal 
Abstract: Sodium-ion batteries (SIBs) have caught considerable attention in last few years owing to the abundance of sodium in comparison to lithium. The commercial graphite anode is demonstrated unsuitable as an anode material for SIBs due to the larger radius of Na+ ions, whereas the transition metal dichalcogenides (TMDs) show great potential as anodes for SIBs because of their high achievable capacity. The sluggish kinetics, large volume expansion, and aggregation of those materials however results in severe decay of the electrochemical performance. In this work, a flower-like MoSe2/C composite is synthesized with ethylenediamine and cassava starch (denoted as MoSe2/C-cas) and designed based on these principles: 1) expand the d-spacing of (0 0 2) planes of MoSe2 to enhance the kinetics for the intercalation- deintercalation of Na+ ions and 2) embed MoSe2 into the carbon matrix to enhance the conductivity and restrict the volume expansion and aggregation of MoSe2. As a result, MoSe2/C-cas exhibits superior cycle performance and rate capability for sodium storage. It shows durable long-life cycle capability with a reversible capacity of 360 mAhg(-1) after 350 cycles at 0.5 Ag-1. At the current density of 4 Ag-1, the reversible capacity is still maintained at 266 mAhg(-1).
URI: http://hdl.handle.net/10397/75763
ISSN: 0947-6539
EISSN: 1521-3765
DOI: 10.1002/chem.201702791
Appears in Collections:Journal/Magazine Article

Access
View full-text via PolyU eLinks SFX Query
Show full item record

SCOPUSTM   
Citations

15
Last Week
1
Last month
Citations as of Dec 6, 2018

WEB OF SCIENCETM
Citations

11
Last Week
0
Last month
Citations as of Dec 13, 2018

Page view(s)

17
Last Week
1
Last month
Citations as of Dec 9, 2018

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.