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Title: Synthesis, structures of mononuclear and dinuclear iron(II) complexes supported by non-symmetric guanidinate(amidinate) ligands
Authors: Wang, H
Guo, Z 
Tong, H
Zhou, M
Keywords: Amidinate
Crystal structures
Iron(II) complexes
Issue Date: 2018
Publisher: Elsevier Ltd
Source: Polyhedron, 2018, v. 141, p. 100-104 How to cite?
Journal: Polyhedron 
Abstract: A new family of Fe(II) compounds, 1–3, have been prepared, which are derived from the non-symmetric lithium guanidinate Li(L1) [L1 = N(Ph)C(R)N(SiMe3)] (R = 1-piperidino) or the lithium amidinates Li(L2) [L2 = N(Ph)C(Ph)N(SiMe3)] or Li(L3) [L3 = N(2,6-iPr2C6H3)C(Ph)N(SiMe3)]. Treatment of Li(L1), Li(L2) or Li(L3) with anhydrous FeCl2 afforded [(L1)4Fe2] (1), [(L2)4Fe2] (2) or [{L3}2Fe] (3), respectively. The molecular structures of 1–3 were determined by an X-ray diffraction study.
EISSN: 0277-5387
DOI: 10.1016/j.poly.2017.11.027
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