Please use this identifier to cite or link to this item:
Title: Highly water-absorbing silk yarn with interpenetrating network via in situ polymerization
Authors: Lee, KI
Wang, X
Guo, X 
Yung, KF
Fei, B 
Keywords: In situ polymerization
Water absorption
Issue Date: 2017
Publisher: Elsevier
Source: International journal of biological macromolecules, 2017, v. 95, p. 826-832 How to cite?
Journal: International journal of biological macromolecules 
Abstract: Silk was modified via in situ polymerization of two monomers acrylamide and sodium acrylate by swelling in an effective LiBr dissolution system. Swelling of natural silks in LiBr solutions of low concentration was clearly observed under optical microscope, and their conformational changes were revealed by X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. Dissolution tests and FTIR spectra of these modified silks suggested the presence of interpenetrating network of polyacrylamide and poly(sodium acrylate) in the silk yarns. These modified silks exhibited superior water absorption to that of raw silk and greatly improved mechanical properties in both dry and wet states. These novel modified silks also showed low cytotoxicity towards skin keratinocytes, having potential applications in biomedical textiles. This modification method by in situ polymerization after swelling in LiBr provides a new route to highly enhance the properties and performance of silk for various applications.
EISSN: 0141-8130
DOI: 10.1016/j.ijbiomac.2016.11.090
Appears in Collections:Journal/Magazine Article

View full-text via PolyU eLinks SFX Query
Show full item record


Last Week
Last month
Citations as of Apr 21, 2018

Page view(s)

Last Week
Last month
Citations as of Apr 23, 2018

Google ScholarTM



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.