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Title: Wheel-to-rhomboid isomerization as well as nitrene transfer catalysis of ruthenium-thiolate wheels
Authors: Tso, KCH
Chan, SLF 
Huang, JS
Che, CM
Issue Date: 2017
Publisher: Royal Society of Chemistry
Source: Chemical communications, 2017, v. 53, no. 16, p. 2419-2422 How to cite?
Journal: Chemical communications 
Abstract: A unique ruthenium-thiolate molecular rhomboid (⋄)-[Ru(SAr)2(CO)2]8, which consists of eight octahedra linked by alternate face- and vertex-sharing, was produced by isomerization of the molecular wheel (○)-[Ru(SAr)2(CO)2]8 at elevated temperature. The use of a (○)-[Ru(SAr)2(CO)2]6 wheel for catalytic aziridination of alkenes via nitrene transfer is also described.
ISSN: 1359-7345
EISSN: 1364-548X
DOI: 10.1039/c6cc09903c
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