Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/63747
Title: Assembly of a 3D nanoporous framework [Cu6(OH)4(tib)8]n8+ from Cu(II) and the flexible tripodal ligand tib
Authors: Liu, HK
Tan, HY
Cai, JW
Zhou, ZY
Chan, ASC
Liao, S
Xiao, W
Zhang, HX
Yu, XL
Kang, BS
Issue Date: 2001
Publisher: Royal Society of Chemistry
Source: Chemical communications, 2001, p. 1008-1009 How to cite?
Journal: Chemical communications 
Abstract: The structural characterization of a 3D nanoporous complex {[Cu6(tib)8(OH)4](OH)8 ·22H2O·4MeOH}n 1 [tib = 1,3,5-tris- (imidazol-1-ylmethyl)benzene] assembled from the tripodal ligand tib and Cu(MeCO2)2 shows that π–π interactions resulting from the novel T-shaped conformation of the ligand are the key trigger for the construction of the backbone of a framework with channels of size 12.00 × 18.91 and 10.30 × 13.66 Å.
URI: http://hdl.handle.net/10397/63747
ISSN: 1359-7345
EISSN: 1364-548X
DOI: 10.1039/B100325I
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