Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/63741
Title: Preparation, characterization, and reactivity of an osmium alkenyl dihydrogen complex
Authors: Liu, SH
Lo, ST
Wen, TB
Zhou, ZY
Lau, CP
Jia, G
Issue Date: 2001
Publisher: American Chemical Society
Source: Organometallics, 2001, v. 20, no. 4, p. 667-672 How to cite?
Journal: Organometallics 
Abstract: Treatment of OsCl2(PPh3)(PNP) (PNP = 2,6-(Ph2PCH2)2C5H3N) with LiC⋮CPh produced OsCl(PPh3)(2-Ph2PCH(CPhCH)-6-Ph2PCH2C5H3N). The structure of the latter, unusual complex has been confirmed by an X-ray diffraction study. Reaction of OsCl(PPh3)(2-Ph2PCH(CPhCH)-6-Ph2PCH2C5H3N) with H2 and K2CO3 in the presence of NaBF4 in methanol produced OsH(PPh3)(2-Ph2PCH(CPhCH)-6-Ph2PCH2C5H3N). Protonation of OsH(PPh3)(2-Ph2PCH(CPhCH)-6-Ph2PCH2C5H3N) with HBF4 gave [Os(H2)(PPh3)(2-Ph2PCH(CPhCH)-6-Ph2PCH2C5H3N)]BF4, which reacted with H2 to give [OsH(H2)(PPh3)(2-Ph2PCH(CPhCH2)-6-Ph2PCH2C5H3N)]BF4.
URI: http://hdl.handle.net/10397/63741
ISSN: 0276-7333
EISSN: 1520-6041
DOI: 10.1021/om000818t
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