Please use this identifier to cite or link to this item:
http://hdl.handle.net/10397/62506
DC Field | Value | Language |
---|---|---|
dc.contributor | Department of Applied Biology and Chemical Technology | - |
dc.creator | Zhang, SH | - |
dc.creator | Jiang, YM | - |
dc.creator | Ma, W | - |
dc.creator | Zhou, ZY | - |
dc.date.accessioned | 2017-01-09T01:18:57Z | - |
dc.date.available | 2017-01-09T01:18:57Z | - |
dc.identifier.issn | 0254-5861 | - |
dc.identifier.uri | http://hdl.handle.net/10397/62506 | - |
dc.language.iso | en | en_US |
dc.publisher | 中國學術期刊(光盤版)電子雜誌社 | en_US |
dc.rights | © 2005 中国学术期刊电子杂志出版社。本内容的使用仅限于教育、科研之目的。 | en_US |
dc.rights | © 2005 China Academic Journal Electronic Publishing House. It is to be used strictly for educational and research purposes. | en_US |
dc.subject | Nickel complex | en_US |
dc.subject | Taurine-salicylaldehyde Schiff base | en_US |
dc.subject | Crystal structure | en_US |
dc.subject | Dimmer | en_US |
dc.title | Synthesis, characterization and structure of the dimmer complex [ni(tssb)(phen)h2o]·c2h5oh·0.5h2o | en_US |
dc.type | Journal/Magazine Article | en_US |
dc.identifier.spage | 633 | - |
dc.identifier.epage | 636 | - |
dc.identifier.volume | 24 | - |
dc.identifier.issue | 6 | - |
dc.identifier.doi | 10.14102/j.cnki.0254-5861.2005.06.004 | - |
dcterms.abstract | The title complex [Ni(TSSB)(phen)H2O]?C2H5OH?0.5H2O (C23H26N3NiO6.5S, TSSB = taurine salicylaldehyde Schiff base, phen = 1,10-phenanthroline) has been synthesized by the reaction of taurine salicylaldehyde Schiff base (TSSB), 1,10-phenanthroline and nickel acetate in water-ethanol. Its single-crystal structure was determined by X-ray diffraction method. The crystal belongs to triclinic, space group P1 with a = 1.0562(2), b = 1.1604(2), c = 2.1170(3) nm, α = 103.257(3), β = 96.958(4), γ = 105.179(3)°, Mr = 539.24, V = 2.3917(6) nm3, Z = 4, Dc = 1.498 g/cm3, μ = 0.945 mm-1 and F(000) = 1124. The compound is a one-dimensional network, infinitely extending with hydrogen bonds. The Ni(Ⅱ) is 6-coordinated by one nitrogen and two oxygen atoms from taurine salicylaldehyde Schiff base, two nitrogen from 1,10-phenanthroline and one oxygen from water to form a distorted octahedronal coordination geometry. | - |
dcterms.accessRights | open access | en_US |
dcterms.bibliographicCitation | 结构化学 (Chinese journal of structural chemistry), 2005, v. 24, no. 6, p. 633-636 | - |
dcterms.isPartOf | 结构化学 (Chinese journal of structural chemistry) | - |
dcterms.issued | 2005 | - |
dc.identifier.rosgroupid | r29257 | - |
dc.description.ros | 2005-2006 > Academic research: refereed > Publication in refereed journal | - |
dc.description.oa | Version of Record | en_US |
dc.identifier.FolderNumber | OA_IR/PIRA | en_US |
dc.description.pubStatus | Published | en_US |
Appears in Collections: | Journal/Magazine Article |
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File | Description | Size | Format | |
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r29257.pdf | 515.06 kB | Adobe PDF | View/Open |
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