Please use this identifier to cite or link to this item: http://hdl.handle.net/10397/62443
Title: A benzo[c]carbazolyl-based phosphine ligand for Pd-catalyzed tetra-ortho-substituted biaryl syntheses
Authors: Fu, WC
Zhou, ZY
Kwong, F 
Issue Date: 2016
Publisher: Royal Society of Chemistry
Source: Organic chemistry frontiers, 2016, v. 3, no. 2, p. 273-276 How to cite?
Journal: Organic chemistry frontiers 
Abstract: A new benzo[c]carbazolyl-based phosphine ligand has been designed and synthesized. This newly developed ligand efficiently facilitates the Pd-catalyzed tetra-ortho-substituted biaryl syntheses via Suzuki-Miyaura cross-coupling. With 1 mol% of the Pd(OAc)(2)/L6 catalyst, sterically congested biaryls were afforded in good-to-excellent yields. In particular, the mild reaction conditions exhibited good compatibility of heterocycles and functional groups including esters and nitrile. L6 was structurally characterized by X-ray crystallographic analysis.
URI: http://hdl.handle.net/10397/62443
ISSN: 2052-4129
DOI: 10.1039/c5qo00400d
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